{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,30]],"date-time":"2026-10-30T18:12:01Z","timestamp":1793383921407,"version":"4.5.0"},"reference-count":112,"publisher":"Wiley","issue":"27","license":[{"start":{"date-parts":[[2025,5,23]],"date-time":"2025-05-23T00:00:00Z","timestamp":1747958400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2025,5,23]],"date-time":"2025-05-23T00:00:00Z","timestamp":1747958400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["INST 40\/575\u20131 FUGG"],"award-info":[{"award-number":["INST 40\/575\u20131 FUGG"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,7]]},"abstract":"Abstract<\/jats:title>\n \n A one\u2010pot synthesis for previously unknown heavy homologues of Group 9 metal carbynes [(Me\n 3<\/jats:sub>\n P)\n 3<\/jats:sub>\n Co\u2261GeAr*] (\n 1<\/jats:bold>\n ), [(Me\n 3<\/jats:sub>\n P)\n 3<\/jats:sub>\n Rh\u2261GeAr*] (\n 2<\/jats:bold>\n ), [(Me\n 3<\/jats:sub>\n P)\n 3<\/jats:sub>\n Ir\u2261GeAr*] (\n 3<\/jats:bold>\n ), [(Me\n 3<\/jats:sub>\n P)\n 3<\/jats:sub>\n Ir\u2261SnAr*] (\n 5<\/jats:bold>\n ), and [(Et\n 3<\/jats:sub>\n P)\n 3<\/jats:sub>\n Ir\u2261PbAr*] (\n 7<\/jats:bold>\n ) is presented [Ar* = C\n 6<\/jats:sub>\n H\n 3<\/jats:sub>\n \u20102,6\u2010(Trip)\n 2<\/jats:sub>\n , Trip\u00a0=\u00a02,4,6\u2010C\n 6<\/jats:sub>\n H\n 2<\/jats:sub>\n i<\/jats:italic>\n Pr\n 3<\/jats:sub>\n ]. During these preparations, the tetrylidynes [(Me\n 3<\/jats:sub>\n P)\n 3<\/jats:sub>\n Rh\u2261SnAr*] (\n 4<\/jats:bold>\n ), and [(Me\n 3<\/jats:sub>\n P)\n 3<\/jats:sub>\n Rh\u2261PbAr*] (\n 6<\/jats:bold>\n ), were also prepared in a one\u2010pot procedure. In a hitherto unknown metathetical exchange reaction, the transition metal plumbylidynes were converted into the respective stannylidynes in reaction with terphenyl stannylene chloride, and the germylidynes were formed from the corresponding stannylidynes in reaction with terphenyl germylene chloride. These metathesis reactions were tracked by\n 31<\/jats:sup>\n P{\n 1<\/jats:sup>\n H} NMR spectroscopy, which shows complete exchange of the tetrel [EAr]\u2010fragment and the formation of an intermediate in the rhodium plumbylidyne reaction with stannylene chloride (Ar\u00a0=\u00a0Ar*, Tbb). Reactions of the tetrylidynes (\n 2<\/jats:bold>\n \u2013\n 5<\/jats:bold>\n ) with carbon dioxide yield the products of a redox reaction [(Me\n 3<\/jats:sub>\n P)\n 3<\/jats:sub>\n (CO)M\u2010E(\n \u03b7<\/jats:italic>\n 2<\/jats:sup>\n \u2010O\n 2<\/jats:sub>\n CO\u2010\n \u03ba<\/jats:italic>\n 2<\/jats:sup>\n O<\/jats:italic>\n )Ar*] [E\u00a0=\u00a0Ge, M\u00a0=\u00a0Rh (\n 11<\/jats:bold>\n ); M\u00a0=\u00a0Ir (\n 12<\/jats:bold>\n ); E\u00a0=\u00a0Sn, M\u00a0=\u00a0Rh (\n 14<\/jats:bold>\n ), M\u00a0=\u00a0Ir (\n 16<\/jats:bold>\n )] with a carbon monoxide coordinated at the transition metal and a carbonate coordinated at the Group 14 element. For tin the intermediates formed by mono CO\n 2<\/jats:sub>\n addition [(Me\n 3<\/jats:sub>\n P)\n 3<\/jats:sub>\n M(\n \u03bc<\/jats:italic>\n ,\n \u03b7<\/jats:italic>\n 2<\/jats:sup>\n \u2010CO\n 2<\/jats:sub>\n \u2010\n \u03baC<\/jats:italic>\n :\n \u03baO<\/jats:italic>\n )SnAr*] [M\u00a0=\u00a0Rh (\n 13<\/jats:bold>\n ), M\u00a0=\u00a0Ir (\n 15<\/jats:bold>\n )] have been isolated.\n <\/jats:p>","DOI":"10.1002\/anie.202503930","type":"journal-article","created":{"date-parts":[[2025,4,24]],"date-time":"2025-04-24T06:13:59Z","timestamp":1745475239000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Metathetical Exchange, Synthesis, and Carbon Dioxide Addition of Higher Homologues of Group 9 Metal Carbynes"],"prefix":"10.1002","volume":"64","author":[{"given":"Lennart G.","family":"Holzapfel","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie, Eberhard Karls Universit\u00e4t 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Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Klaus","family":"Eichele","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie, Eberhard Karls Universit\u00e4t T\u00fcbingen Auf der Morgenstelle 18 72076 T\u00fcbingen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4701-4410","authenticated-orcid":false,"given":"Lars","family":"Wesemann","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie, Eberhard Karls Universit\u00e4t T\u00fcbingen Auf der Morgenstelle 18 72076 T\u00fcbingen 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