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The carboxylic acid additive significantly increases both reactivity and enantioselectivity, allowing for the highly efficient generation of chiral 1,2\u2010diols with up to 99% ee. The application utility is proved through derivations and a total synthesis of (\n                    <jats:italic>R<\/jats:italic>\n                    )\u2010(\u2212)\u2010eliprodil. 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