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A primary challenge in industrializing CO\n                    <jats:sub>2<\/jats:sub>\n                    RR technologies for producing liquid fuel is the mass transfer limitation of CO\n                    <jats:sub>2<\/jats:sub>\n                    , which significantly reduces the current density of CO\n                    <jats:sub>2<\/jats:sub>\n                    RR. This study proposes a new enzyme\u2010enhanced electrocatalysis platform for boosting CO\n                    <jats:sub>2<\/jats:sub>\n                    RR current density. This platform integrates an enzyme of bovine carbonic anhydrase (bCA), stabilized on carbon nanotubes (bCA@CNT), into formate\/formic acid selective metal catalysts such as tin (Sn) and bismuth (Bi) to prepare Metal\u2010bCA (M\u2010bCA) hybrid cathodes. The incorporation of bCA enhances both the CO\n                    <jats:sub>2<\/jats:sub>\n                    hydration and the reversible dehydration of bicarbonate to CO\n                    <jats:sub>2<\/jats:sub>\n                    in the cathode. This dynamic catalysis of bCA facilitates rapid local regeneration of dissolved CO\n                    <jats:sub>2<\/jats:sub>\n                    from bicarbonate at the catalyst surface, thereby boosting the current density of CO\n                    <jats:sub>2<\/jats:sub>\n                    RR. Consequently, the formate current density of the Sn\u2010bCA cathode was 3.3 times higher than that of the bare Sn cathode in a membrane\u2010electrode assembly (MEA)\u2010type cell. Furthermore, the Bi\u2010bCA cathode achieved an excellent\u00a0current density of\u00a0442\u00a0mA\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , 1.5 times higher than the bare Bi cathode, for direct production of highly concentrated (3.4\u00a0mol\u00a0L\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) formic acid\u00a0in a 3\u2010compartment cell.\n                  <\/jats:p>","DOI":"10.1002\/anie.202504380","type":"journal-article","created":{"date-parts":[[2025,4,27]],"date-time":"2025-04-27T22:35:12Z","timestamp":1745793312000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Boosting Current Density of Electrocatalytic CO\n                    <sub>2<\/sub>\n                    Reduction using Metal\u2013Enzyme Hybrid Cathodes"],"prefix":"10.1002","volume":"64","author":[{"given":"Yeomin","family":"Kang","sequence":"first","affiliation":[{"name":"Department of Chemical Engineering Konkuk University 120 Neungdong\u2010ro, Gwangjin\u2010gu Seoul 05029 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yunjae","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biological Engineering Korea University 145 Anam\u2010ro, Seongbuk\u2010gu Seoul 02841 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Youngjin","family":"Doh","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering Konkuk University 120 Neungdong\u2010ro, Gwangjin\u2010gu Seoul 05029 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinwoo","family":"Lee","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Korea Advanced Institute of 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