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To meet the requirements of POV\u2010MOPs with varied sizes, synthetic strategies including reconstruction of original vertex, introduction of exogenous vertex, and initiative of polyhedral interlock have been developed, which successfully integrated a pair of tetrahedral monomers into an hourglass\u2010shaped dimer. On top of this, several structuring principles, such as anisotropic enhancement, electrostatic potential reduction, and sufficient intramolecular support, can be drawn from here and popularized to the related MOP systems. Thanks to the advent of such splicing techniques managed by both covalent and non\u2010covalent interactions, the close communication of POV\u2010MOPs has afforded not only the unprecedented structural archetypes, but the unique behaviors for NH\n                    <jats:sub>3<\/jats:sub>\n                    adsorption as well.\n                  <\/jats:p>","DOI":"10.1002\/anie.202504424","type":"journal-article","created":{"date-parts":[[2025,5,20]],"date-time":"2025-05-20T05:56:42Z","timestamp":1747720602000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Splicing Them Together: Construction of Polyoxovanadate\u2013Organic Polyhedra\u2010Based Pyrgoscages and Catenanes"],"prefix":"10.1002","volume":"64","author":[{"given":"Ke\u2010Wei","family":"Tong","sequence":"first","affiliation":[{"name":"College of Chemistry and Chemical Engineering Advanced Catalytic Engineering Research Center of the Ministry of Education Hunan University  Changsha 410082 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan\u2010Hu","family":"Wang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering Advanced Catalytic Engineering Research Center of the Ministry of Education Hunan University  Changsha 410082 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing","family":"Du","sequence":"additional","affiliation":[{"name":"College of Chemistry and Materials Science Testing and Analysis Center Hebei Normal University  Shijiazhuang 050024 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chao\u2010Qin","family":"Chen","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering Advanced Catalytic Engineering Research Center of the Ministry of Education Hunan University  Changsha 410082 P.R. 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