{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,22]],"date-time":"2026-01-22T07:23:26Z","timestamp":1769066606445,"version":"3.49.0"},"reference-count":39,"publisher":"Wiley","issue":"23","license":[{"start":{"date-parts":[[2025,4,4]],"date-time":"2025-04-04T00:00:00Z","timestamp":1743724800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/100007633","name":"Stiftelsen f\u00f6r Milj\u00f6strategisk Forskning","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100007633","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004359","name":"Vetenskapsr\u00e5det","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004359","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004063","name":"Knut och Alice Wallenbergs Stiftelse","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004063","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,6,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Conversion of carbon dioxide (CO\u2082) into value\u2010added products is aimed to develop scalable technologies to promote a circular economy. While the electrochemical reduction of CO\u2082 to carbon monoxide (CO) and formic acid has advanced significantly, a major challenge remains achieving further reduced and more energy\u2010dense products, such as methanol (MeOH), through sustainable pathways. Herein, we report a molecular electrode capable of direct six\u2010electron reduction of CO\u2082 to MeOH using water as a proton source with a global Faradaic efficiency (FE<jats:sub>G<\/jats:sub>) of 22% and product selectivity of 61% for MeOH. The design consists of an active copper\u2010hydride center surrounded by two closely spaced benzimidazole\u2013hydride units, facilitating the catalytic transfer of three hydrides to produce MeOH. The concurrent formation of formic acid and the absence of formaldehyde suggest that MeOH is generated via a formato pathway. DFT investigations revealed the complete mechanistic pathway, which supports the experimental observations. The morphology and stability of the electrode were evaluated before and after prolonged electrolysis (12\u00a0h) experiments using electron microscopic techniques.<\/jats:p>","DOI":"10.1002\/anie.202504783","type":"journal-article","created":{"date-parts":[[2025,3,25]],"date-time":"2025-03-25T23:27:38Z","timestamp":1742945258000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Molecularly Designed Cathode for Copper\u2010Benzimidazole\u2010Induced CO<sub>2<\/sub> Reduction to MeOH"],"prefix":"10.1002","volume":"64","author":[{"given":"Pamela","family":"Bengtsson","sequence":"first","affiliation":[{"name":"Department of Organic Chemistry Arrhenius Laboratory, Stockholm University  Stockholm 10691 Sweden"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Victor","family":"Liebgott","sequence":"additional","affiliation":[{"name":"Department of Organic Chemistry Arrhenius Laboratory, Stockholm University  Stockholm 10691 Sweden"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lars","family":"Eriksson","sequence":"additional","affiliation":[{"name":"Department of Materials and Environmental Chemistry Stockholm University  Stockholm 10691 Sweden"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kjell","family":"Jansson","sequence":"additional","affiliation":[{"name":"Department of Materials and Environmental Chemistry Stockholm University  Stockholm 10691 Sweden"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Cheuk\u2010Wai","family":"Tai","sequence":"additional","affiliation":[{"name":"Department of Materials and Environmental Chemistry Stockholm University  Stockholm 10691 Sweden"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Amrendra K.","family":"Singh","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Indore  Simrol Indore 453552 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bel\u00e9n","family":"Mart\u00edn\u2010Matute","sequence":"additional","affiliation":[{"name":"Department of Organic Chemistry Arrhenius Laboratory, Stockholm University  Stockholm 10691 Sweden"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Biswanath","family":"Das","sequence":"additional","affiliation":[{"name":"Department of Organic Chemistry Arrhenius Laboratory, Stockholm University  Stockholm 10691 Sweden"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2025,4,4]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcou.2014.12.001"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsengineeringau.3c00049"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3GC01892J"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2023.140185"},{"key":"e_1_2_6_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c06878"},{"key":"e_1_2_6_6_1","first-page":"328","volume-title":"Methanol Production and Applications: An Overview","author":"Dalena F.","year":"2018"},{"key":"e_1_2_6_7_1","unstructured":"NexantECA Glob. Methanol Mark. Snapshot2024."},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.144227"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2023.215081"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2018.10.001"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2015.04.055"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.rineng.2022.100711"},{"key":"e_1_2_6_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2010.12.036"},{"key":"e_1_2_6_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcou.2021.101720"},{"key":"e_1_2_6_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201909257"},{"key":"e_1_2_6_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-019-1760-8"},{"key":"e_1_2_6_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202310623"},{"key":"e_1_2_6_18_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-024-01190-9"},{"key":"e_1_2_6_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtener.2023.101382"},{"key":"e_1_2_6_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c05669"},{"key":"e_1_2_6_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.4c00301"},{"key":"e_1_2_6_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201900401"},{"key":"e_1_2_6_23_1","doi-asserted-by":"publisher","DOI":"10.3390\/ma12233902"},{"key":"e_1_2_6_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b09653"},{"key":"e_1_2_6_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8SC02535E"},{"key":"e_1_2_6_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00705"},{"key":"e_1_2_6_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0162-0134(02)00577-9"},{"key":"e_1_2_6_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00366"},{"key":"e_1_2_6_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202104377"},{"key":"e_1_2_6_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b00378"},{"key":"e_1_2_6_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.0c10125"},{"key":"e_1_2_6_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3TA00071K"},{"key":"e_1_2_6_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-020-0548-7"},{"key":"e_1_2_6_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202200538"},{"key":"e_1_2_6_35_1","doi-asserted-by":"publisher","DOI":"10.3389\/fchem.2024.1469804"},{"key":"e_1_2_6_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c14605"},{"key":"e_1_2_6_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/wcms.1606"},{"key":"e_1_2_6_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b11474"},{"key":"e_1_2_6_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.5b10763"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202504783","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,3]],"date-time":"2025-10-03T07:08:16Z","timestamp":1759475296000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202504783"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,4,4]]},"references-count":39,"journal-issue":{"issue":"23","published-print":{"date-parts":[[2025,6,2]]}},"alternative-id":["10.1002\/anie.202504783"],"URL":"https:\/\/doi.org\/10.1002\/anie.202504783","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,4,4]]},"assertion":[{"value":"2025-02-27","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-03-25","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-04-04","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202504783"}}