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This study rises to the challenge by pioneering a hybrid acid\/alkali formaldehyde hydrogen production fuel cell (h\u2010AAFHFC), an integrated system that integrates anodic partial electro\u2010reforming of aldehydes at low potential with the cathodic hydrogen evolution reaction (HER). The device introduces a new self\u2010powered paradigm for hydrogen generation, driven by electrochemical neutralization energy (ENE), featuring high Faradaic efficiency for hydrogen production, co\u2010generation of electricity, and HCOOH. The h\u2010AAFHFC attains an open\u2010circuit voltage (OCV) of 1.11\u00a0V and a peak power density of 94\u00a0mW cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , enabling simultaneous hydrogen production at both electrodes with an extraordinary Faradaic efficiency of approximately 200%. This breakthrough marks a transformative shift, moving from traditional electricity\u2010driven systems to self\u2010sustaining H\n                    <jats:sub>2<\/jats:sub>\n                    generation. Our work demonstrates a promising pathway for sustainable hydrogen production, advancing the potential of clean hydrogen energy technologies.\n                  <\/jats:p>","DOI":"10.1002\/anie.202504894","type":"journal-article","created":{"date-parts":[[2025,4,15]],"date-time":"2025-04-15T06:50:46Z","timestamp":1744699846000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Self\u2010Powered Electrocatalytic Aldehyde Reforming Fuel Cell for Sustainable H\n                    <sub>2<\/sub>\n                    Generation with \u223c200% Faradaic Efficiency"],"prefix":"10.1002","volume":"64","author":[{"given":"Fen","family":"Hu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Structural Chemistry and Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou, Fujian 350002 P.R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junxiang","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry and Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou, Fujian 350002 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Suqin","family":"Ci","sequence":"additional","affiliation":[{"name":"Fujian Provincial Key Laboratory of Soil Environmental Health and Regulation College of Resources and Environment Fujian Agriculture and Forestry University  Fuzhou, Fujian 350002 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenhai","family":"Wen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry and Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou, Fujian 350002 P.R. China"},{"name":"University of Chinese Academy of Sciences  Beijing 100049 P.R. 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