{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T08:21:36Z","timestamp":1793089296329,"version":"4.5.0"},"reference-count":70,"publisher":"Wiley","issue":"28","license":[{"start":{"date-parts":[[2025,4,26]],"date-time":"2025-04-26T00:00:00Z","timestamp":1745625600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001348","name":"Agency for Science, Technology and Research","doi-asserted-by":"publisher","award":["M22K2c0078"],"award-info":[{"award-number":["M22K2c0078"]}],"id":[{"id":"10.13039\/501100001348","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,7,7]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Traditional understanding of electrocatalytic reactions has primarily focused on the covalent interactions between adsorbates and catalyst surfaces, often overlooking the significant influence of the electrolyte on the catalytic process. Recently, researchers have highlighted the pivotal role of cations in the electrolyte, demonstrating their capability to modulate the reaction pathways and thus the activity and selectivity. These findings underscore the need for a deeper, atomic\u2010level understanding of the electrode\u2013electrolyte interface. This perspective presents the mechanisms through which cations affect electrocatalysis, with a focus on the hydrogen\u2010bond network, the adsorption behavior of reaction intermediates, the electric field within the electrochemical double layer, and the local electronic properties of catalysts. It provides a summary of the influences of cations on various electrocatalytic reactions, including hydrogen oxidation reaction (HOR), hydrogen evolution reaction (HER), oxygen evolution reaction (OER), oxygen reduction reaction (ORR), nitrogen reduction reaction (NRR), nitrate reduction reaction (NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    RR), and carbon dioxide reduction reaction (CO\n                    <jats:sub>2<\/jats:sub>\n                    RR). At the end, future research directions are provided to maximize the potential of leveraging the cation effects in the design of more efficient electrolyte systems.\n                  <\/jats:p>","DOI":"10.1002\/anie.202505022","type":"journal-article","created":{"date-parts":[[2025,4,18]],"date-time":"2025-04-18T02:43:31Z","timestamp":1744944211000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":101,"title":["Mechanistic Insights into Cation Effects in Electrolytes for Electrocatalysis"],"prefix":"10.1002","volume":"64","author":[{"given":"Qian","family":"Wu","sequence":"first","affiliation":[{"name":"School of Material Science and Engineering Nanyang Technological University  50 Nanyang Avenue Singapore 639798 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhichuan J.","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Material Science and Engineering Nanyang Technological University  50 Nanyang Avenue Singapore 639798 Singapore"},{"name":"Center for Advanced Catalysis Science and Technology Nanyang Technological University  50 Nanyang Avenue Singapore 639798 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,4,26]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00679"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202306103"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202402184"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2318652121"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CS00913K"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adh9487"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-44896-x"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b06765"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c00639"},{"key":"e_1_2_8_10_1","author":"Yuan Y.","year":"2025","journal-title":"Angew. 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