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The methyl groups of the triangular ligands guide the rectangular ligands to adopt a \u201clandscape\u201d orientation to avoid steric hindrance. This small structural change gives rise to an enlarged interior cavity volume for guest encapsulation, as compared with a previously\u2010reported trigonal prismatic capsule, where the same rectangular ligand took a \u201cportrait\u201d orientation with a non\u2010methylated triangular ligand of similar size. The methylated triangular ligand contains a boron core, which can bind fluoride ions that point inward. These bound fluorides serve as hydrogen bond acceptors, which increases the affinity of the capsule for hydrogen\u2010bond\u2010donating alcohols, which are bound in preference to ketones of similar sizes. Moreover, this boron\u2010containing trigonal prism selectively binds perrhenate over perchlorate, while fluoride binding modulates the cavity charge, leading to perrhenate ejection. These and similar\n                    <jats:italic>endo<\/jats:italic>\n                    \u2010functionalized capsules may thus be of use in the fields of molecular recognition and separation.\n                  <\/jats:p>","DOI":"10.1002\/anie.202505137","type":"journal-article","created":{"date-parts":[[2025,5,8]],"date-time":"2025-05-08T11:23:53Z","timestamp":1746703433000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Fluoride Enhances Alcohol Binding Within a Trigonal\u2010Prismatic Metal\u2010Organic Capsule"],"prefix":"10.1002","volume":"64","author":[{"given":"Yuchong","family":"Yang","sequence":"first","affiliation":[{"name":"Yusuf Hamied Department of Chemistry University of Cambridge  Cambridge CB2 1EW U.K."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tanya K.","family":"Ronson","sequence":"additional","affiliation":[{"name":"Yusuf Hamied Department of Chemistry University of Cambridge  Cambridge CB2 1EW U.K."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dingyu","family":"Hou","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering University College London  London WC1E 7JE U.K."},{"name":"Beijing National Laboratory for Molecular Sciences, Institute of Chemistry Chinese Academy of Sciences  Beijing 100190 P.R. 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