{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T22:07:19Z","timestamp":1789596439932,"version":"build-2803163510"},"reference-count":71,"publisher":"Wiley","issue":"25","license":[{"start":{"date-parts":[[2025,4,26]],"date-time":"2025-04-26T00:00:00Z","timestamp":1745625600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,6,17]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The continuous development of novel catalytic approaches is crucial for advancing efficient CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation processes. Drawing inspiration from single\u2010atom catalysis and 2D materials, we designed a new 2D single\u2010atom catalyst with excellent thermal stability by thermally treating Cu\u2010adsorbed \u03b3\u2010AlOOH nanosheets, which yielded a Cu\/\u03b3\u2010Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    catalyst with high activity in the hydrogenation of CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010yielding methanol (CH\n                    <jats:sub>3<\/jats:sub>\n                    OH), dimethyl ether (DME), and CO as products. The active Cu sites are monodispersed and highly stable due to their cationic oxidation state and their substitution for pentacoordinated aluminum (Al\n                    <jats:sup>P<\/jats:sup>\n                    ) sites on particle surfaces. This study demonstrates an efficient approach for achieving a high CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation rate (30.45\u00a0mol mol\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) using a catalyst system that lacks metallic Cu centers, traditionally considered essential for H\u2082 dissociation, and employs what was previously thought to be an inert metal oxide (\u03b3\u2010Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    ) for CO and CH\n                    <jats:sub>3<\/jats:sub>\n                    OH production. Ongoing mechanistic studies aim to elucidate the synergy between cationic Cu single atoms and \u03b3\u2010Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    , a Lewis acid support, in facilitating hydrogen (H\n                    <jats:sub>2<\/jats:sub>\n                    ) activation and methanol formation.\n                  <\/jats:p>","DOI":"10.1002\/anie.202505444","type":"journal-article","created":{"date-parts":[[2025,4,17]],"date-time":"2025-04-17T22:07:01Z","timestamp":1744927621000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Boosting Hydrogenation of CO\n                    <sub>2<\/sub>\n                    Using Cationic Cu Atomically Dispersed on 2D \u03b3\u2010Al\n                    <sub>2<\/sub>\n                    O\n                    <sub>3<\/sub>\n                    Nanosheets"],"prefix":"10.1002","volume":"64","author":[{"given":"Ping","family":"Chen","sequence":"first","affiliation":[{"name":"Physical &amp; Computational Science Directorate Pacific Northwest National Laboratory  Richland WA 99354 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yifeng","family":"Zhu","sequence":"additional","affiliation":[{"name":"Physical &amp; Computational Science Directorate Pacific Northwest National Laboratory  Richland WA 99354 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hailin","family":"Zhang","sequence":"additional","affiliation":[{"name":"Physical &amp; Computational Science Directorate Pacific Northwest National Laboratory  Richland WA 99354 USA"},{"name":"Institute of Process Engineering Chinese Academy of Sciences  Beijing 100190 P.R. 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