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Screening catalysts with stable phases and robust crystal structures appears to be a feasible approach to counteract the reduction corrosion. In this work, with the guidance of computational predictions, a tetragonal phase In\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>3<\/jats:sub>\n                    electrocatalyst is designed through a self\u2010healing strategy for the conversion of CO\n                    <jats:sub>2<\/jats:sub>\n                    to formate. Remarkably, In\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>3<\/jats:sub>\n                    exhibits superior stability for over 200\u00a0h at a current density of \u223c210\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , with a persistent formate faradaic efficiency of \u223c97%. A series of in situ spectroscopic measurements confirm that In\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>3<\/jats:sub>\n                    maintains the structural and valence state integrity throughout the reaction. Combined with density functional theory calculations, the performance enhancement mechanism and self\u2010healing principle of In\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>3<\/jats:sub>\n                    are clearly elucidated. This work provides a novel perspective for the design of highly efficient and stable CO\n                    <jats:sub>2<\/jats:sub>\n                    RR electrocatalysts.\n                  <\/jats:p>","DOI":"10.1002\/anie.202505587","type":"journal-article","created":{"date-parts":[[2025,5,27]],"date-time":"2025-05-27T06:35:14Z","timestamp":1748327714000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Self\u2010Healing Indium Sulfide Catalyst for Efficient and Robust Electrocatalytic CO2 Conversion"],"prefix":"10.1002","volume":"64","author":[{"given":"Haiyan","family":"Wu","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering, School of Marine Science and Engineering Hainan University  Haikou 570228 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yansong","family":"Zhou","sequence":"additional","affiliation":[{"name":"State Key Laboratory of 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