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Here, we develop an interweaved porous coating based on a kind of covalent organic framework (ODH\u2500Cu<jats:sub>3<\/jats:sub>\u2500COF) based helical nanofibers through the assembly of non\u2010linear oxalyldihydrazide unit and rigid Cu<jats:sub>3<\/jats:sub> unit. The interweaved helical nanofibers network with well\u2010arranged polar groups (i.e., C\u2550N, \u2500CO\u2500NH\u2500, and pyrazole groups) could serve as nuclei sites to achieve fast Li<jats:sup>+<\/jats:sup> insertion\/extraction and dendrite suppression in high\u2010rate conditions. Benefiting from the advantages of interface design, the resultant ODH\u2500Cu<jats:sub>3<\/jats:sub>\u2500COF modified anode improves the Coulombic efficiency (97.5%, 120 cycles at 5\u00a0mA cm<jats:sup>\u22122<\/jats:sup>) and showcases a stable lifespan (1000\u00a0h at 2\u00a0mA cm<jats:sup>\u22122<\/jats:sup> and 2 mAh cm<jats:sup>\u22122<\/jats:sup>) in symmetric cell. Moreover, the high\u2010rate property of ODH\u2500Cu<jats:sub>3<\/jats:sub>\u2500COF@Li||LFP full cell presents an excellent cycling stability (900 cycles at 5 C) in commercial carbonate electrolyte. Theoretical calculations reveal that lithiophilic ODH\u2500Cu<jats:sub>3<\/jats:sub>\u2500COF has high Li affinity to reduce the nucleation barrier and achieve fast desolvation process in an interface to promote the lifespan of high\u2010rate lithium\u2010metal batteries.<\/jats:p>","DOI":"10.1002\/anie.202505626","type":"journal-article","created":{"date-parts":[[2025,3,27]],"date-time":"2025-03-27T23:14:06Z","timestamp":1743117246000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Interweaved Nanofiber Anode Coating Based on Covalent Organic Frameworks for High\u2010Performance Lithium\u2010Metal Batteries"],"prefix":"10.1002","volume":"64","author":[{"given":"Huifen","family":"Zhuang","sequence":"first","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Carbon Dioxide Resource Utilization, South China Normal University, School of Chemistry Guangzhou 510006 P.R. 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