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In this study, we report a hexagonal close\u2010packed (hcp)\u2010PdMo catalyst that exhibits the highest room temperature catalytic activity for CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation to methanol among reported catalysts, with 100% methanol selectivity and without any signs of deactivation. Structural analyses, which included various in situ and ex situ X\u2010ray techniques and infrared spectroscopy, have revealed that Mo and Pd serve as the active sites for CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption and H\n                    <jats:sub>2<\/jats:sub>\n                    dissociation, respectively. The CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation reaction is facilitated at room temperature on the surface of the hcp\u2010PdMo intermetallic catalyst, where the adjacently arranged Pd and Mo sites play important roles in methanol synthesis. Mechanistic studies, combined with density functional theory (DFT) calculations, have demonstrated that the reaction proceeds via a reverse water\u2010gas shift and subsequent CO hydrogenation (R&amp;C) pathway though a Pd\u2010assisted Mo redox mechanism at room temperature. These findings not only reveal the origin of the reaction mechanism for methanol synthesis but also open a new direction for the design of highly efficient catalysts that function under mild conditions.\n                  <\/jats:p>","DOI":"10.1002\/anie.202505634","type":"journal-article","created":{"date-parts":[[2025,5,26]],"date-time":"2025-05-26T02:40:47Z","timestamp":1748227247000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Origin of Room Temperature Methanol Synthesis over Hcp\u2010PdMo"],"prefix":"10.1002","volume":"64","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1799-8829","authenticated-orcid":false,"given":"Feilong","family":"Xing","sequence":"first","affiliation":[{"name":"MDX Research Center for Element Strategy Institute of Integrated Research Institute of Science Tokyo  4259 Nagatsuta, Midori\u2010ku Yokohama 226\u20138503 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