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To preserve their voltage advantage, developing effective structural design strategies is essential. However, the lack of material descriptors hampers the efficiency of material design and screening. Herein, two material descriptors: the benzene ring\/active nitrogen (R\/N) ratio and energy density factor (E\n                    <jats:sub>f<\/jats:sub>\n                    ) are established to guide high\u2010energy density SMB design. As proof of concept, triphenylamine (TPA, 3 R\/N ratio and 573.6\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>f<\/jats:sub>\n                    value) and a porous organic polymer condensation of triiodotriphenylamine and dihydrophenazine named p\u2010PZA POP (1.5 R\/N ratio and 907.5\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>f<\/jats:sub>\n                    value) are chosen. As a result, the p\u2010PZA POP achieves a high energy density of 524.6\u00a0Wh kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 1\u00a0A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , nearly double that of TPA (273.3\u00a0Wh kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). Remarkably, p\u2010PZA POP demonstrates excellent wide\u2010temperature electrochemical performance from 50\u00a0\u00b0C (166.2\u00a0mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 1\u00a0A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) to \u221220\u00a0\u00b0C (141.6\u00a0mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.1\u00a0A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). This work establishes a theoretical framework for the rational design and screening of high\u2010performance p\u2010type OEMs through predictive material descriptors.\n                  <\/jats:p>","DOI":"10.1002\/anie.202505831","type":"journal-article","created":{"date-parts":[[2025,5,3]],"date-time":"2025-05-03T00:00:09Z","timestamp":1746230409000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":22,"title":["P\u2010type Cathode Material Design Guided by Material Descriptors for High\u2010Energy Density Sodium Batteries"],"prefix":"10.1002","volume":"64","author":[{"given":"Weijia","family":"Zhang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Advanced Chemical Power Sources, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Centre, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Frontiers Science Center for New Organic Matter, College of Chemistry Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tianjiang","family":"Sun","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Chemical Power Sources, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Centre, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Frontiers Science Center for New Organic Matter, College of Chemistry Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weichao","family":"Cheng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Chemical Power Sources, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Centre, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Frontiers Science Center for New Organic Matter, College of Chemistry Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengyao","family":"Shi","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Chemical Power Sources, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Centre, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Frontiers Science Center for New Organic Matter, College of Chemistry Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Min","family":"Cheng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Chemical Power Sources, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Centre, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Frontiers Science Center for New Organic Matter, College of Chemistry Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiong","family":"Sun","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Chemical Power Sources, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Centre, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Frontiers Science Center for New Organic Matter, College of Chemistry Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianfei","family":"Su","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Chemical Power Sources, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Centre, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Frontiers Science Center for New Organic Matter, College of Chemistry Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiulan","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Chemical Power Sources, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Centre, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Frontiers Science Center for New Organic Matter, College of Chemistry Nankai University  Tianjin 300071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhanliang","family":"Tao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Chemical Power Sources, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Centre, Collaborative 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