{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T18:08:26Z","timestamp":1790878106884,"version":"4.1.0"},"reference-count":50,"publisher":"Wiley","issue":"33","license":[{"start":{"date-parts":[[2025,6,25]],"date-time":"2025-06-25T00:00:00Z","timestamp":1750809600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100003819","name":"Natural Science Foundation of Hubei Province","doi-asserted-by":"publisher","award":["2025AFA008"],"award-info":[{"award-number":["2025AFA008"]}],"id":[{"id":"10.13039\/501100003819","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,8,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Transition\u2010metal\u2010free aluminosilicate FER\u2010type zeolite has been demonstrated to effectively catalyze methane to methanol using N\n                    <jats:sub>2<\/jats:sub>\n                    O as the oxidant with distorted tetra\u2010coordinated aluminum (Al\n                    <jats:sub>IV\u20102<\/jats:sub>\n                    ) and penta\u2010coordinated aluminum (Al\n                    <jats:sub>V<\/jats:sub>\n                    ) as potential active sites. However, the specific effects of Al distribution on the active Al species have not been thoroughly investigated. Herein, aluminosilicate FER\u2010type zeolites with controllable Al distribution were developed. Al distribution, including the arrangement and location of Al atoms, was characterized using\n                    <jats:sup>27<\/jats:sup>\n                    Al MQMAS\/MAS and\n                    <jats:sup>29<\/jats:sup>\n                    Si MAS NMR spectra. The arrangement of aluminum, particularly the isolated Al and paired Al in as\u2010synthesized samples, influenced the proximity between oxidative and acidic sites in H\u2010type samples. Al locations involved the specific positioning of bifunctional sites and affected the final product. The increased CH\n                    <jats:sub>4<\/jats:sub>\n                    conversion at 250\u2013275 \u00b0C of FER zeolite with Al preferential population at T4 sites confirmed the higher activity of Al species from T4 sites. Additionally, a higher proportion of Al atoms in 10\u2010ring channels facilitated the tandem conversion of methane to methanol on oxidative sites, followed by methanol to hydrocarbons on acidic sites at 300\u2013375\u00a0\u00b0C. This study corroborated and expanded upon our recent research and highlighted the significant impact of Al distribution in FER zeolite on methane oxidation.\n                  <\/jats:p>","DOI":"10.1002\/anie.202506023","type":"journal-article","created":{"date-parts":[[2025,6,18]],"date-time":"2025-06-18T03:35:33Z","timestamp":1750217733000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Aluminum Distribution in Ferrierite Zeolites Influences the Performance of Methane Oxidation"],"prefix":"10.1002","volume":"64","author":[{"given":"Peipei","family":"Xiao","sequence":"first","affiliation":[{"name":"Institute of Integrated Research Institute of Science Tokyo  4259 Nagatsuta, Midori\u2010ku Yokohama 226\u20108501 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaomin","family":"Tang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Magnetic Resonance Spectroscopy and Imaging, National Center for Magnetic Resonance in Wuhan, Innovation Academy for Precision Measurement Science and Technology Chinese Academy of Sciences  Wuhan 430071 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hiroto","family":"Toyoda","sequence":"additional","affiliation":[{"name":"Institute of Integrated Research Institute of Science Tokyo  4259 Nagatsuta, Midori\u2010ku Yokohama 226\u20108501 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yilin","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute of Integrated Research Institute of Science Tokyo  4259 Nagatsuta, Midori\u2010ku Yokohama 226\u20108501 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anmin","family":"Zheng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Magnetic Resonance Spectroscopy and Imaging, National Center for Magnetic Resonance in Wuhan, Innovation Academy for Precision Measurement Science and Technology Chinese Academy of Sciences  Wuhan 430071 China"},{"name":"Interdisciplinary Institute of NMR and Molecular Sciences, Hubei Province for Coal Conversion and New Carbon Materials, School of Chemistry and Chemical Engineering Wuhan University of Science and Technology  Wuhan 430081 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lizhuo","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemical and Biomolecular Engineering the University of Sydney  Sydney New South Wales 2006 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Huang","sequence":"additional","affiliation":[{"name":"School of Chemical and Biomolecular Engineering the University of Sydney  Sydney New South Wales 2006 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Masato","family":"Sawada","sequence":"additional","affiliation":[{"name":"Institute of Integrated Research Institute of Science Tokyo  4259 Nagatsuta, Midori\u2010ku Yokohama 226\u20108501 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kengo","family":"Nakamura","sequence":"additional","affiliation":[{"name":"Institute of Integrated Research Institute of Science Tokyo  4259 Nagatsuta, Midori\u2010ku Yokohama 226\u20108501 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yong","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute of Integrated Research Institute of Science Tokyo  4259 Nagatsuta, Midori\u2010ku Yokohama 226\u20108501 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hermann","family":"Gies","sequence":"additional","affiliation":[{"name":"Institute of Integrated Research Institute of Science Tokyo  4259 Nagatsuta, Midori\u2010ku Yokohama 226\u20108501 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3315-3172","authenticated-orcid":false,"given":"Toshiyuki","family":"Yokoi","sequence":"additional","affiliation":[{"name":"Institute of Integrated Research Institute of Science Tokyo  4259 Nagatsuta, Midori\u2010ku Yokohama 226\u20108501 Japan"},{"name":"iPEACE223 Inc.  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