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However, the construction of molecular structures with exquisite topologies and specific properties based on molecular weaving is still in its infancy. Herein, we designed and fabricated a two\u2010dimensional (2D) woven covalent organic polymer (COP) network (named as\n                    <jats:bold>CityU\u201046<\/jats:bold>\n                    ) driven by the dative N\u2192B bonds between the 1,4\u2010bis(benzodioxa\u2010borole)benzene (BACT) and 2,5\u2010bis(4\u2010pyridyl)\u20101,3,4\u2010thiadiazole (BPT). The complex woven topology of\n                    <jats:bold>CityU\u201046<\/jats:bold>\n                    was determined using a single\u2010crystal X\u2010ray diffraction technique, revealing that it features a well\u2010defined two\u2010over and two\u2010under interweaving pattern at the molecular level. Due to its structural merits,\n                    <jats:bold>CityU\u201046<\/jats:bold>\n                    can be used as an artificial organic solid\u2010electrolyte interphase layer on the surface of Li metal anodes, significantly improving the stability and long\u2010term performance of lithium metal cells.\n                  <\/jats:p>","DOI":"10.1002\/anie.202506036","type":"journal-article","created":{"date-parts":[[2025,5,5]],"date-time":"2025-05-05T05:19:32Z","timestamp":1746422372000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":27,"title":["Interweaving Covalent Organic Polymer Chains Into Two\u2010Dimensional Networks: Synthesis, Single Crystal Structure, and Application for Stabilizing Lithium Metal Anode"],"prefix":"10.1002","volume":"64","author":[{"given":"Lizhong","family":"He","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering City University of Hong Kong  Tat Chee Avenue Kowloon Tong Hong Kong SAR P.R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fangyuan","family":"Kang","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering City University of Hong Kong  Tat Chee Avenue Kowloon Tong Hong Kong SAR P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinglun","family":"Yang","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering City University of Hong Kong  Tat Chee Avenue Kowloon Tong Hong Kong SAR P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zihao","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering City University of Hong Kong  Tat Chee Avenue Kowloon Tong Hong Kong SAR P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aimin","family":"Yu","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biotechnology Swinburne University of Technology  Hawthorn VIC 3122 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dong\u2010Sheng","family":"Li","sequence":"additional","affiliation":[{"name":"College of Materials and Chemical Engineering Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials China Three Gorges University  Yichang 443002 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Libao","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Powder Metallurgy Central South University  Changsha 410083 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qichun","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering City University of Hong Kong  Tat Chee Avenue Kowloon Tong Hong Kong SAR P.R. China"},{"name":"Department of Chemistry Center of Super\u2010Diamond and Advanced Films (COSDAF) &amp; Hong Kong Institute of Clean Energy (HKICE) City University of Hong Kong  Hong Kong SAR 999077 P.R. China"},{"name":"City University of Hong Kong Shenzhen Research Institute  Shenzhen Guangdong 518057 P.R. 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