{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,24]],"date-time":"2026-10-24T20:38:25Z","timestamp":1792874305638,"version":"4.5.0"},"reference-count":43,"publisher":"Wiley","issue":"32","license":[{"start":{"date-parts":[[2025,6,10]],"date-time":"2025-06-10T00:00:00Z","timestamp":1749513600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22071070"],"award-info":[{"award-number":["22071070"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22272006"],"award-info":[{"award-number":["22272006"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,8,4]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The availability of active sites and the electronic structure of metal heterogeneous catalysts are crucial to maximize their catalytic performance. In this study, we describe a new and efficient catalyst system, C\n                    <jats:sub>60<\/jats:sub>\n                    fullerenolamine (FA)\u2010modified Pd metallene (Pdene), and demonstrate that the FA molecules not only increase the active sites availability but also exert an electronic effect that enhances the catalytic performance of Pdene in alcohol oxidation reactions. Specifically, FA increases the electrochemical active surface area through dispersion, while its electron\u2010withdrawing characteristics induce an electron\u2010deficient surface on Pdene, which facilitates the adsorption of electron\u2010rich intermediates (OH\n                    <jats:sup>*<\/jats:sup>\n                    ) and the desorption of electron\u2010deficient poisonous intermediates (CO\n                    <jats:sup>*<\/jats:sup>\n                    ). The practical significance of this modification is demonstrated by achieving a 54.5% increase in mass activity and 46.3% enhancement in specific activity for ethanol oxidation relative to Pdene. Beyond these improvements, the FA\u2010Pdene catalyst demonstrates exceptional operational stability, superior CO poisoning resistance, and enhanced C1 pathway selectivity. An in\u2010depth analysis utilizing in\u2010situ Fourier transform infrared spectroscopy, coupled with density functional theory calculations, offers valuable insights into how the FA ligand modulates the mechanistic pathways involved in ethanol oxidation processes. This fullerene\u2010mediated catalytic effect could hold the key to unlocking the potential of the metal\u2010based system.\n                  <\/jats:p>","DOI":"10.1002\/anie.202506044","type":"journal-article","created":{"date-parts":[[2025,6,5]],"date-time":"2025-06-05T03:29:53Z","timestamp":1749094193000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":34,"title":["Electronic Modulation and Active Site Exposure Using C\n                    <sub>60<\/sub>\n                    Fullerenolamine Enable High\u2010Performance Alcohol Oxidation on Pd Metallene Catalysts"],"prefix":"10.1002","volume":"64","author":[{"given":"Shuqian","family":"Xie","sequence":"first","affiliation":[{"name":"State Key Laboratory of Materials Processing and Die &amp; Mould Technology School of Materials Science and Engineering Huazhong University of Science and Technology  Wuhan 430074 P.R. 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