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Enhancing these complexes with photosensitivity and photooxidation capabilities, aiming to create multifunctional molecular devices, presents significant challenges. In response to these challenges, we successfully designed and synthesized three innovative metal complexes. The complexes demonstrate a remarkable ability to perform CO\n                    <jats:sub>2<\/jats:sub>\n                    photoreduction in tandem with methanol photooxidation, allowing for the simultaneous production of formic acid without requiring additional photosensitizers and electron sacrificial reductants. An optimal turnover number (TON) value of 855 was obtained under simulated sunlight. Even under natural sunlight, the TON can reach 207, much higher than the value of the physical mixture of the photocatalytic reductive and oxidative moieties. Spectroscopic studies and density functional theory (DFT) calculations revealed that integrating reduction and oxidation sites in one molecular catalyst can promote charge transfer kinetics and enhance activity for CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction and methanol oxidation. This is the first report that non\u2010noble metal homogeneous catalysts can simultaneously possess photosensitivity, photoreduction, and photo\u2010oxidation functions, offering new insights into designing homogeneous catalysts for artificial photosynthesis.\n                  <\/jats:p>","DOI":"10.1002\/anie.202506060","type":"journal-article","created":{"date-parts":[[2025,4,16]],"date-time":"2025-04-16T03:04:41Z","timestamp":1744772681000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["Self\u2010Photosensitizing Cobalt Complexes for Photocatalytic CO\n                    <sub>2<\/sub>\n                    Reduction Coupled with CH\n                    <sub>3<\/sub>\n                    OH Oxidation"],"prefix":"10.1002","volume":"64","author":[{"given":"Ji\u2010Hong","family":"Zhang","sequence":"first","affiliation":[{"name":"Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology  Tianjin 300384 China"},{"name":"Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle Nanchang Hangkong University  Nanchang 330063 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhao\u2010Ming","family":"Ge","sequence":"additional","affiliation":[{"name":"Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology  Tianjin 300384 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Di\u2010Chang","family":"Zhong","sequence":"additional","affiliation":[{"name":"Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology  Tianjin 300384 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing\u2010Lin","family":"Zuo","sequence":"additional","affiliation":[{"name":"School of Chemistry &amp; Chemical Engineering State Key Lab Coordination Chemistry Nanjing University  Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marc","family":"Robert","sequence":"additional","affiliation":[{"name":"Institut Parisien de Chimie Mol\u00e9culaire Sorbonne Universit\u00e9, CNRS, IPCM  Paris F\u201075005 France"},{"name":"Institut Universitaire de France (IUF)  Paris F\u201075005 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tong\u2010Bu","family":"Lu","sequence":"additional","affiliation":[{"name":"Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and Engineering Tianjin University of Technology  Tianjin 300384 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,4,27]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-019-1554-z"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar900209b"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.4c09970"},{"key":"e_1_2_7_4_1","first-page":"55687","volume":"107","author":"Davis S.","year":"2010","journal-title":"Proc. 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