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The crystallization kinetics of dynamic wet film during spin coating differs widely from the static wet film during R2R fabrication, which makes the existing crystallization control strategies become inapplicable while upscaling. The crystallization regulation of static wet film remains a critical challenge, particularly under ambient conditions. In this study, we employed the antisolvent\u2010bathing method that can efficiently regulate the crystallization process of static wet films made by drop coating. Through systematic investigation of solvent\u2010antisolvent interdiffusion kinetics and in\u2010situ crystallization monitoring via time\u2010resolved UV\u2013Vis spectroscopy, we identify alkyl chlorides (particularly chloroform) as optimal bathing agents. The champion device made by CF bathing achieved an efficiency of 24.49% under ambient conditions (RH 30%\u201350%), representing the highest efficiency for perovskite solar cells made by the antisolvent bathing method. The device showed negligible decay after 2256\u00a0h storage in N\n                    <jats:sub>2<\/jats:sub>\n                    atmosphere. The method demonstrates exceptional environmental resilience to humidity and solvent accumulation, accompanied by an ultra\u2010wide processing window (10\u00a0s\u201310\u00a0min bathing duration, &gt;2\u00a0min post\u2010bathing delay tolerance).\n                  <\/jats:p>","DOI":"10.1002\/anie.202506418","type":"journal-article","created":{"date-parts":[[2025,7,9]],"date-time":"2025-07-09T16:24:38Z","timestamp":1752078278000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["Antisolvent\u2010Bathing Strategy with Ultra\u2010Wide Processing Window for Making High\u2010efficiency Perovskite Solar Cells in Ambient Air"],"prefix":"10.1002","volume":"64","author":[{"given":"Lixiu","family":"Zhang","sequence":"first","affiliation":[{"name":"Center for Excellence in Nanoscience (CAS) Key Laboratory of Nanosystem and Hierarchical Fabrication (CAS), National Center for Nanoscience and Technology  Beijing 100190 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