{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,26]],"date-time":"2026-10-26T19:30:13Z","timestamp":1793043013898,"version":"4.5.0"},"reference-count":53,"publisher":"Wiley","issue":"33","license":[{"start":{"date-parts":[[2025,6,25]],"date-time":"2025-06-25T00:00:00Z","timestamp":1750809600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22172006"],"award-info":[{"award-number":["22172006"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22472007"],"award-info":[{"award-number":["22472007"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22288102"],"award-info":[{"award-number":["22288102"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22272007"],"award-info":[{"award-number":["22272007"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,8,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Hydrogen production through low\u2010temperature methanol steam reforming (MSR) reaction plays a critical role in the development of new energy but remains a great challenge. Herein, we report a Cu\/Zn(Ga)O\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    catalyst, which is prepared via an interface reconstruction strategy. Interestingly, this catalyst is featured with a unique mortise\u2010and\u2010tenon structure: Cu nanoparticles are embedded into the Zn(Ga)O\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    substrate, which ensures a stable Zn\u2013O\u2013Cu\n                    <jats:sup>+<\/jats:sup>\n                    \u2013O\n                    <jats:italic>\n                      <jats:sub>v<\/jats:sub>\n                    <\/jats:italic>\n                    \u2013Ga\n                    <jats:italic>\n                      <jats:sup>\u03b4<\/jats:sup>\n                    <\/jats:italic>\n                    <jats:sup>+<\/jats:sup>\n                    interface structure. The resulting Cu\/Zn(Ga)O\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    catalyst exhibits 99.3% CH\n                    <jats:sub>3<\/jats:sub>\n                    OH conversion with an H\n                    <jats:sub>2<\/jats:sub>\n                    production rate of 124.6\u00a0\u00b5mol\u00a0g\n                    <jats:sub>cat<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00a0s\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 225\u00a0\u00b0C, which is preponderant to the state\u2010of\u2010the\u2010art catalysts. Furthermore, an ultra\u2010high catalytic stability was demonstrated through a 400\u00a0h stream\u2010on\u2010line test without obvious decline. Kinetic isotope analysis, in situ spectroscopy characterizations, and theoretical calculations reveal that the MSR reaction over Cu\/Zn(Ga)O\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    catalyst follows the formaldehyde oxidation route. The CH\n                    <jats:sub>3<\/jats:sub>\n                    O* and H\n                    <jats:sub>2<\/jats:sub>\n                    O molecule adsorb at the adjacent Cu\n                    <jats:sup>+<\/jats:sup>\n                    \u2212O\n                    <jats:italic>\n                      <jats:sub>v<\/jats:sub>\n                    <\/jats:italic>\n                    interface (intrinsic active site) with an oxygen\u2010terminal adsorption configuration, which promotes electron transfer from the\n                    <jats:italic>d<\/jats:italic>\n                    \u2010band center of Cu to the O (\n                    <jats:italic>s<\/jats:italic>\n                    ,\n                    <jats:italic>p<\/jats:italic>\n                    )\u2010band of the substrate molecule. This significantly reduces the energy barrier of C\u2500H bond cleavage in CH\n                    <jats:sub>3<\/jats:sub>\n                    O* dehydrogenation (the rate\u2010determining step) and H\n                    <jats:sub>2<\/jats:sub>\n                    O dissociation, accounting for the extraordinarily enhanced H\n                    <jats:sub>2<\/jats:sub>\n                    production.\n                  <\/jats:p>","DOI":"10.1002\/anie.202506458","type":"journal-article","created":{"date-parts":[[2025,6,12]],"date-time":"2025-06-12T06:09:05Z","timestamp":1749708545000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":44,"title":["Embedded\u2010Type Cu Nanoparticle with Largely Enhanced Catalytic Activity and Stability Toward Methanol Steam Reforming"],"prefix":"10.1002","volume":"64","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6494-0825","authenticated-orcid":false,"given":"Hao","family":"Meng","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical Technology  Beijing 100029 P.R. China"},{"name":"Quzhou Institute for Innovation in Resource Chemical Engineering  Quzhou 324000 P.R. China"},{"name":"Department of Applied Biology and Chemical Technology The Hong Kong Polytechnic University  Kowloon Hong Kong SAR 999077 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tianyao","family":"Shen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical Technology  Beijing 100029 P.R. China"},{"name":"Yusuf Hamied Department of Chemistry University of Cambridge  Lensfield Road Cambridge CB2 1EW UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiming","family":"Yin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical Technology  Beijing 100029 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0624-3241","authenticated-orcid":false,"given":"Yusen","family":"Yang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical Technology  Beijing 100029 P.R. China"},{"name":"Quzhou Institute for Innovation in Resource Chemical Engineering  Quzhou 324000 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6662-2967","authenticated-orcid":false,"given":"Jian","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical Technology  Beijing 100029 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kai","family":"Feng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical Technology  Beijing 100029 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shaoteng","family":"Yuan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical Technology  Beijing 100029 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical Technology  Beijing 100029 P.R. China"},{"name":"Quzhou Institute for Innovation in Resource Chemical Engineering  Quzhou 324000 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Enze","family":"Xu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical Technology  Beijing 100029 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lirong","family":"Zheng","sequence":"additional","affiliation":[{"name":"Institute of High Energy Physics Chinese Academy of Sciences  Beijing 100049 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Song","family":"Hong","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical Technology  Beijing 100029 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9744-3067","authenticated-orcid":false,"given":"Feng\u2010Shou","family":"Xiao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical Technology  Beijing 100029 P.R. China"},{"name":"Key Lab of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5257-790X","authenticated-orcid":false,"given":"Min","family":"Wei","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical Technology  Beijing 100029 P.R. China"},{"name":"Quzhou Institute for Innovation in Resource Chemical Engineering  Quzhou 324000 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,6,25]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-019-0364-x"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-023-01040-0"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c09102"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adp6034"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1095"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-27116-8"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202300406"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c12603"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abm3371"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b00058"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-022-00870-8"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-33847-z"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-28474-7"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202407025"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-38883-x"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202003208"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c01522"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c13355"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c08902"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adp7379"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202304303"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-16674-y"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adf6984"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-020-03130-6"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c03895"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202423269"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c02918"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c07386"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2020.119052"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abm9257"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms2242"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-28476-5"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-27557-1"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-021-00729-4"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.122839"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-43679-0"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202105118"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c04504"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202410381"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c00981"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-47397-z"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-46513-3"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202404418"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-023-01392-x"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.1c01369"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2020.09.018"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/cs3007507"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.2732745"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c10728"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2019.118016"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.3389\/fchem.2021.678112"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp801252d"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-10854-1"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202506458","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,12,1]],"date-time":"2025-12-01T14:52:37Z","timestamp":1764600757000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202506458"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,6,25]]},"references-count":53,"journal-issue":{"issue":"33","published-print":{"date-parts":[[2025,8,11]]}},"alternative-id":["10.1002\/anie.202506458"],"URL":"https:\/\/doi.org\/10.1002\/anie.202506458","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,6,25]]},"assertion":[{"value":"2025-03-20","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-06-11","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-06-25","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202506458"}}