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Herein, we report the fabrication of a bimetallic glassy MOF via a liquid\u2013liquid transition process. This is achieved by introducing a robust Schiff base\u2013cobalt functional group into Zn\u2010ZIF\u201062, which attracts negatively charged imidazolate ligands, facilitating low\u2010temperature melting. This ultimately leads to the formation of a bimetallic glassy MOF (Co\/Zn\u2010a\n                    <jats:sub>g<\/jats:sub>\n                    ZIF\u201062\u2010ipy) upon melt\u2010quenching. The material features an exceptionally high glass\u2010forming capability, uniformly distributed bimetallic ions, and a markedly enhanced visible light photogeneration efficiency of enzymatically active nicotinamide adenine dinucleotide (NADH) when compared with Co\u2010doped ZIF\u201062 glass. These findings offer novel insights into modulating the liquid phase of an MOF to develop functional glassy MOF photocatalysts for coenzyme NADH regeneration and other advanced applications.\n                  <\/jats:p>","DOI":"10.1002\/anie.202506570","type":"journal-article","created":{"date-parts":[[2025,6,5]],"date-time":"2025-06-05T04:30:32Z","timestamp":1749097832000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Engineering a Meltable MOF to Tune Liquid Transition and Promote Coenzyme Regeneration"],"prefix":"10.1002","volume":"64","author":[{"given":"Wengang","family":"Huang","sequence":"first","affiliation":[{"name":"School of Chemical Engineering The University of Queensland  Saint Lucia QLD 4072 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wen\u2010Long","family":"Xue","sequence":"additional","affiliation":[{"name":"Anorganische Chemie, Fakult\u00e4t f\u00fcr Chemie und Chemische Biologie Technische Universit\u00e4t Dortmund  Otto\u2010Hahn Stra\u00dfe 6 44227 Dortmund Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Peng","family":"Chen","sequence":"additional","affiliation":[{"name":"Australian Institute for Bioengineering and Nanotechnology The University of Queensland  Saint Lucia QLD 4072 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Zhiliang","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering The University of Queensland  Saint Lucia QLD 4072 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Rijia","family":"Lin","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering The University of Queensland  Saint Lucia QLD 4072 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shuke","family":"Zhao","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering The University of Queensland  Saint Lucia QLD 4072 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shuwen","family":"Yu","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering The University of Queensland  Saint Lucia QLD 4072 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yuelei","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering The University of Queensland  Saint Lucia QLD 4072 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiangyi","family":"Zha","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering The University of Queensland  Saint Lucia QLD 4072 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dominique","family":"Appadoo","sequence":"additional","affiliation":[{"name":"Australian Synchrotron  800 Blackburn Rd Clayton VIC 3168 Australia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tian","family":"Tian","sequence":"additional","affiliation":[{"name":"Department of Applied Biology and Chemical Technology The Hong Kong Polytechnic University  Hung Hom Hong Kong SAR P.R. 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