{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,20]],"date-time":"2026-10-20T16:29:36Z","timestamp":1792513776479,"version":"4.5.0"},"reference-count":30,"publisher":"Wiley","issue":"31","license":[{"start":{"date-parts":[[2025,6,16]],"date-time":"2025-06-16T00:00:00Z","timestamp":1750032000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2020YFA0210903"],"award-info":[{"award-number":["2020YFA0210903"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22225807"],"award-info":[{"award-number":["22225807"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21961132026"],"award-info":[{"award-number":["21961132026"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22021004"],"award-info":[{"award-number":["22021004"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["KO 2261\/11\u20101"],"award-info":[{"award-number":["KO 2261\/11\u20101"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,7,28]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Although PtGaO\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    \u2010containing catalysts are active and selective in the non\u2010oxidative dehydrogenation of propane (PDH) to propylene, they suffer from rapid deactivation and, especially, inability to recover their initial performance in a series of PDH\/oxidative regeneration cycles, characteristics that are highly relevant to commercialization. Herein, we identified reducibility of GaO\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    as the key descriptor affecting the above catalyst features. Oxidized GaO\n                    <jats:sub>x<\/jats:sub>\n                    species are more active than reduced GaO\n                    <jats:sub>x<\/jats:sub>\n                    in the recombination of two H species formed from propane, which is the rate\u2010limiting step in the PDH reaction. This process is further accelerated by Pt. The reduction of GaO\n                    <jats:sub>x<\/jats:sub>\n                    with time on propane stream leads to catalyst deactivation. Easily reducible GaO\n                    <jats:sub>x<\/jats:sub>\n                    also tend to form PtGaO\n                    <jats:sub>x<\/jats:sub>\n                    under PDH conditions, from which Pt atoms present in fresh catalysts cannot be completely recovered during oxidative regeneration, which is detrimental to catalyst durability. Regardless of the reaction atmosphere, Pt single atoms exist on the surface of PtGaO\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    \u2010containing catalysts with hardly reducible GaO\n                    <jats:sub>x<\/jats:sub>\n                    . Based on the knowledge derived, we developed a catalyst with 500\u00a0ppm Pt on the surface of mixed GaAlO\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    , which outperforms almost all previous PtGaO\n                    <jats:sub>x<\/jats:sub>\n                    \u2010containing catalysts in terms of space\u2010time yield of propylene formation and shows durable operation under industrially relevant conditions.\n                  <\/jats:p>","DOI":"10.1002\/anie.202506704","type":"journal-article","created":{"date-parts":[[2025,5,19]],"date-time":"2025-05-19T03:49:39Z","timestamp":1747626579000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["The Role of Reducibility of PtGaO\n                    <i>\n                      <sub>x<\/sub>\n                    <\/i>\n                    \u2010Based Catalysts for Efficient and Durable Propane Dehydrogenation"],"prefix":"10.1002","volume":"64","author":[{"given":"Kai","family":"Wu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing China University of Petroleum  Beijing 102249 China"},{"name":"Department: Advanced Methods for Applied Catalysis Leibniz\u2010Institut f\u00fcr Katalyse e. V  Albert\u2010Einstein\u2010Str. 29a 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vita A.","family":"Kondratenko","sequence":"additional","affiliation":[{"name":"Department: Advanced Methods for Applied Catalysis Leibniz\u2010Institut f\u00fcr Katalyse e. V  Albert\u2010Einstein\u2010Str. 29a 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingxia","family":"Zhou","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing China University of Petroleum  Beijing 102249 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dmitry E.","family":"Doronkin","sequence":"additional","affiliation":[{"name":"Institute for Chemical Technology and Polymer Chemistry Institute of Catalysis Research and Technology Karlsruhe Institute of Technology  Kaiserstr. 12 D\u201076131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stephan","family":"Bartling","sequence":"additional","affiliation":[{"name":"Department: Advanced Methods for Applied Catalysis Leibniz\u2010Institut f\u00fcr Katalyse e. V  Albert\u2010Einstein\u2010Str. 29a 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiyang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department: Advanced Methods for Applied Catalysis Leibniz\u2010Institut f\u00fcr Katalyse e. V  Albert\u2010Einstein\u2010Str. 29a 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shanlei","family":"Han","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing China University of Petroleum  Beijing 102249 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Jia","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing China University of Petroleum  Beijing 102249 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qi","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing China University of Petroleum  Beijing 102249 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dong","family":"Xiong","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing China University of Petroleum  Beijing 102249 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunming","family":"Xu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing China University of Petroleum  Beijing 102249 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guiyuan","family":"Jiang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing China University of Petroleum  Beijing 102249 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dan","family":"Zhao","sequence":"additional","affiliation":[{"name":"Department: Advanced Methods for Applied Catalysis Leibniz\u2010Institut f\u00fcr Katalyse e. V  Albert\u2010Einstein\u2010Str. 29a 18059 Rostock Germany"},{"name":"Institute for Chemical Technology and Polymer Chemistry Institute of Catalysis Research and Technology Karlsruhe Institute of Technology  Kaiserstr. 12 D\u201076131 Karlsruhe Germany"},{"name":"National Engineering Laboratory for Methanol to Olefins Dalian National Laboratory for Clean Energy iChEM (Collaborative Innovation Center of Chemistry for Energy Materials) Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian 116023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Uwe","family":"Rodemerck","sequence":"additional","affiliation":[{"name":"Department: Advanced Methods for Applied Catalysis Leibniz\u2010Institut f\u00fcr Katalyse e. V  Albert\u2010Einstein\u2010Str. 29a 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"David","family":"Linke","sequence":"additional","affiliation":[{"name":"Department: Advanced Methods for Applied Catalysis Leibniz\u2010Institut f\u00fcr Katalyse e. V  Albert\u2010Einstein\u2010Str. 29a 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0431-6937","authenticated-orcid":false,"given":"Evgenii V.","family":"Kondratenko","sequence":"additional","affiliation":[{"name":"Department: Advanced Methods for Applied Catalysis Leibniz\u2010Institut f\u00fcr Katalyse e. V  Albert\u2010Einstein\u2010Str. 29a 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,6,16]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00814A"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS01140A"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202207756"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-860X(99)00058-7"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2010.06.016"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2010.06.017"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201404460"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-16693-9"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00357G"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.120731"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2021.06.002"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2019.04.027"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b00329"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.15339"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c02553"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.2c00646"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2021.02.129"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.0c22865"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202201453"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-023-01392-x"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10562-017-2028-2"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c00103"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202310062"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.susc.2009.03.022"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.108.195507"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2023.119117"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-860X(97)00124-5"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2007.01.001"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202400081"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b05378"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202506704","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,12,3]],"date-time":"2025-12-03T13:16:59Z","timestamp":1764767819000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202506704"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,6,16]]},"references-count":30,"journal-issue":{"issue":"31","published-print":{"date-parts":[[2025,7,28]]}},"alternative-id":["10.1002\/anie.202506704"],"URL":"https:\/\/doi.org\/10.1002\/anie.202506704","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,6,16]]},"assertion":[{"value":"2025-03-24","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-05-05","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-06-16","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202506704"}}