{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,2]],"date-time":"2026-11-02T23:09:47Z","timestamp":1793660987694,"version":"4.5.1"},"reference-count":40,"publisher":"Wiley","issue":"29","license":[{"start":{"date-parts":[[2025,5,23]],"date-time":"2025-05-23T00:00:00Z","timestamp":1747958400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22371246"],"award-info":[{"award-number":["22371246"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004608","name":"Natural Science Foundation of Jiangsu Province","doi-asserted-by":"publisher","award":["BK20220558"],"award-info":[{"award-number":["BK20220558"]}],"id":[{"id":"10.13039\/501100004608","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,7,14]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The design and synthesis of novel hybrid metal halides polymorphs with full\u2010color tunable emission are critical for the advancement of solid\u2010state lighting and display technologies. However, it remains challenging and rarely reported. Herein, we successfully synthesized three new zero\u2010dimensional (0D) hybrid isomeric copper (I) halides, namely \u03b1\u2010\/\u03b2\u2010\/\u03b3\u2010(BuPh\n                    <jats:sub>3<\/jats:sub>\n                    P)\n                    <jats:sub>2<\/jats:sub>\n                    Cu\n                    <jats:sub>2<\/jats:sub>\n                    I\n                    <jats:sub>4<\/jats:sub>\n                    (where BuPh\n                    <jats:sub>3<\/jats:sub>\n                    P\n                    <jats:sup>+<\/jats:sup>\n                    \u00a0=\u00a0butyltriphenylphosphonium, C\n                    <jats:sub>22<\/jats:sub>\n                    H\n                    <jats:sub>24<\/jats:sub>\n                    P\n                    <jats:sup>+<\/jats:sup>\n                    ), featuring the same edge\u2010sharing [Cu\n                    <jats:sub>2<\/jats:sub>\n                    I\n                    <jats:sub>4<\/jats:sub>\n                    ]\n                    <jats:sup>2\u2212<\/jats:sup>\n                    units. Notably, the monoclinic \u03b1\u2010(BuPh\n                    <jats:sub>3<\/jats:sub>\n                    P)\n                    <jats:sub>2<\/jats:sub>\n                    Cu\n                    <jats:sub>2<\/jats:sub>\n                    I\n                    <jats:sub>4<\/jats:sub>\n                    and \u03b2\u2010(BuPh\n                    <jats:sub>3<\/jats:sub>\n                    P)\n                    <jats:sub>2<\/jats:sub>\n                    Cu\n                    <jats:sub>2<\/jats:sub>\n                    I\n                    <jats:sub>4<\/jats:sub>\n                    , both belonging to the\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>n<\/jats:italic>\n                    space group, exhibit bright blue and orange emission, respectively. The orthorhombic\u2010phase \u03b3\u2010(BuPh\n                    <jats:sub>3<\/jats:sub>\n                    P)\n                    <jats:sub>2<\/jats:sub>\n                    Cu\n                    <jats:sub>2<\/jats:sub>\n                    I\n                    <jats:sub>4<\/jats:sub>\n                    with space group\n                    <jats:italic>Pbca<\/jats:italic>\n                    and larger lattice volume shows vivid red emission, thus achieving tunable full\u2010color emission wavelength spanning from blue (445\u00a0nm) to red (667\u00a0nm), representing the first instance of such broad tunability through adjusting the spatial arrangement of the organic and inorganic parts. Interestingly, \u03b1\u2010(BuPh\n                    <jats:sub>3<\/jats:sub>\n                    P)\n                    <jats:sub>2<\/jats:sub>\n                    Cu\n                    <jats:sub>2<\/jats:sub>\n                    I\n                    <jats:sub>4<\/jats:sub>\n                    undergoes a reversible photo\u2010induced fluorochromism, transitioning from blue to green. Furthermore, a reversible phase transformation between \u03b1\u2010 and \u03b2\u2010(BuPh\n                    <jats:sub>3<\/jats:sub>\n                    P)\n                    <jats:sub>2<\/jats:sub>\n                    Cu\n                    <jats:sub>2<\/jats:sub>\n                    I\n                    <jats:sub>4<\/jats:sub>\n                    can be triggered by dichloromethane and ethyl acetate. As such, a photo\u2010responsive switchable system and a multistage information encryption\/decryption system are successfully devised through leveraging unique multi\u2010stimuli\u2010responsive properties.\n                  <\/jats:p>","DOI":"10.1002\/anie.202506748","type":"journal-article","created":{"date-parts":[[2025,5,14]],"date-time":"2025-05-14T09:39:29Z","timestamp":1747215569000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":52,"title":["Phase Engineering for Achieving Full\u2010Color Tunable Emission from Blue to Red and Multi\u2010Level Information Security in Isomeric Hybrid Copper Halides"],"prefix":"10.1002","volume":"64","author":[{"given":"Jiajing","family":"Wu","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering Yangzhou University  180 Siwangting Road Yangzhou 250002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiao\u2010Feng","family":"Huang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Yangzhou University  180 Siwangting Road Yangzhou 250002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi\u2010Fan","family":"Fu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Yangzhou University  180 Siwangting Road Yangzhou 250002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing\u2010Li","family":"Qi","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Yangzhou University  180 Siwangting Road Yangzhou 250002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li\u2010Xiang","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Yangzhou University  180 Siwangting Road Yangzhou 250002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shu\u2010Fang","family":"Yan","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Yangzhou University  180 Siwangting Road Yangzhou 250002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenlong","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Yangzhou University  180 Siwangting Road Yangzhou 250002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9703-1537","authenticated-orcid":false,"given":"Sheng\u2010Ping","family":"Guo","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Yangzhou University  180 Siwangting Road Yangzhou 250002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,5,23]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abg3989"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abd4860"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202400760"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202400644"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b06940"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202400554"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202411047"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.4c07376"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/lpor.202400799"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202006990"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202407074"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202300731"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.3c00071"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4TC04153D"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202210735"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202200605"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.4c00045"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4QI03036B"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/lpor.202401802"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.4c00318"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3QI01739G"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmaterialslett.4c00371"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.3c02142"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202301937"},{"key":"e_1_2_7_25_1","unstructured":"Deposition umbers 2416601 (for\u03b1\u2010(BuPh3P)2Cu2I4at 296 K) 2416602 (for\u03b2\u2010(BuPh3P)2Cu2I4at 296 K) 2416603 (for\u03b3\u2010(BuPh3P)2Cu2I4at 296 K) 2452686 (for\u03b1\u2010(BuPh3P)2Cu2I4at 100 K) 2452687 (for\u03b2\u2010(BuPh3P)2Cu2I4at 100 K) and 2452688 (for\u03b3\u2010(BuPh3P)2Cu2I4at 100 K) \u00a0contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures service."},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.172.3983.567"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202316449"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevMaterials.3.034604"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abc2181"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202404100"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/agt2.602"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.0c00293"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c14137"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202402409"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202217784"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TC01698A"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2TC01465C"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202212741"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.201800751"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4TC02152E"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202506748","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,11,29]],"date-time":"2025-11-29T18:15:58Z","timestamp":1764440158000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202506748"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,5,23]]},"references-count":40,"journal-issue":{"issue":"29","published-print":{"date-parts":[[2025,7,14]]}},"alternative-id":["10.1002\/anie.202506748"],"URL":"https:\/\/doi.org\/10.1002\/anie.202506748","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,5,23]]},"assertion":[{"value":"2025-03-25","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-05-14","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-05-23","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202506748"}}