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We herein isolate two distinct thirteen\u2010membered silver cluster isomers,\n                    <jats:bold>\n                      Ag\n                      <jats:sub>13<\/jats:sub>\n                      \u2010A\n                    <\/jats:bold>\n                    and\n                    <jats:bold>\n                      Ag\n                      <jats:sub>13<\/jats:sub>\n                      \u2010M\n                    <\/jats:bold>\n                    , in acetone and methanol, respectively. Significantly, we demonstrate the interconversion of these isomers facilitated by solvent manipulation. Mechanistic studies on the solvent\u2010driven\n                    <jats:bold>\n                      Ag\n                      <jats:sub>13<\/jats:sub>\n                      \u2010A\n                    <\/jats:bold>\n                    to\n                    <jats:bold>\n                      Ag\n                      <jats:sub>13<\/jats:sub>\n                      \u2010M\n                    <\/jats:bold>\n                    transformation reveal this transformation proceeds with a low activation energy (23.39 \u00b1 0.81 kcal mol\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and positive entropy, involving counter anion dissociation, ligand twisting, and re\u2010coordination. The observed differences in thermal stability and reactivity between two isomers are attributed to variations in Ag\u2013Ag interactions and surface ligand arrangements, underscoring the critical role of solvent selection in affecting the whole organic transformation through in situ formed clusters. These results highlight the necessity of considering organometallic cluster intermediates in solvent screening.\n                  <\/jats:p>","DOI":"10.1002\/anie.202506860","type":"journal-article","created":{"date-parts":[[2025,4,23]],"date-time":"2025-04-23T01:57:01Z","timestamp":1745373421000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Solvent\u2010Driven Interconversion of Pyridine Dicarbanion\u2010Bonded Ag\n                    <sub>13<\/sub>\n                    Nanocluster Isomers"],"prefix":"10.1002","volume":"64","author":[{"given":"Cong","family":"Jin","sequence":"first","affiliation":[{"name":"Key Laboratory of Bioorganic Phosphorus Chemistry &amp; Chemical Biology (Ministry of Education) Department of Chemistry Tsinghua University  Beijing 100084 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Laboratory of Physical Chemistry of Solid Surfaces Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry Department of Chemistry College of Chemistry and Chemical Engineering Xiamen University  Xiamen 361005 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qianqian","family":"Deng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry Department of Chemistry College of Chemistry and Chemical Engineering Xiamen University  Xiamen 361005 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Keting","family":"Zhou","sequence":"additional","affiliation":[{"name":"Key Laboratory of Bioorganic Phosphorus Chemistry &amp; Chemical Biology (Ministry of Education) Department of Chemistry Tsinghua University  Beijing 100084 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