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Herein, we report three large homoleptic alkynyl\u2010protected silver nanoclusters, [Ag\n                    <jats:sub>98<\/jats:sub>\n                    (2\u2010CH\n                    <jats:sub>3<\/jats:sub>\n                    C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    C\u2261C)\n                    <jats:sub>52<\/jats:sub>\n                    ](BF\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    , [Ag\n                    <jats:sub>86<\/jats:sub>\n                    (2\u2010CH\n                    <jats:sub>3<\/jats:sub>\n                    C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    C\u2261C)\n                    <jats:sub>50<\/jats:sub>\n                    ](BF\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>4<\/jats:sub>\n                    , and [Ag\n                    <jats:sub>74<\/jats:sub>\n                    (2\u2010CH\n                    <jats:sub>3<\/jats:sub>\n                    C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    C\u2261C)\n                    <jats:sub>44<\/jats:sub>\n                    ](BF\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    , synthesized from the same precursor 2\u2010CH\n                    <jats:sub>3<\/jats:sub>\n                    C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    C\u2261CAg via fine\u2010tuning the reduction rate. X\u2010ray crystallography demonstrates that Ino decahedral Ag\n                    <jats:sub>13<\/jats:sub>\n                    units serve as building blocks in all three nanoclusters. Remarkably,\n                    <jats:bold>\n                      Ag\n                      <jats:sub>98<\/jats:sub>\n                    <\/jats:bold>\n                    undergoes an intercluster transformation in methanol. It initially converts into\n                    <jats:bold>\n                      Ag\n                      <jats:sub>74<\/jats:sub>\n                    <\/jats:bold>\n                    , then\n                    <jats:bold>\n                      Ag\n                      <jats:sub>74<\/jats:sub>\n                    <\/jats:bold>\n                    reacts with\n                    <jats:bold>\n                      Ag\n                      <jats:sub>98<\/jats:sub>\n                    <\/jats:bold>\n                    to form\n                    <jats:bold>\n                      Ag\n                      <jats:sub>86<\/jats:sub>\n                    <\/jats:bold>\n                    , which eventually is transformed into the thermodynamically stable\n                    <jats:bold>\n                      Ag\n                      <jats:sub>74<\/jats:sub>\n                    <\/jats:bold>\n                    . Time\u2010dependent electrospray ionization mass spectrometry (ESI\u2010MS) confirms such a multi\u2010step reaction process during the transformation, identifying\n                    <jats:bold>\n                      Ag\n                      <jats:sub>86<\/jats:sub>\n                    <\/jats:bold>\n                    as the key intermediate. Our findings not only provide new insights into the structural transformation pathways of nanoclusters but also enhance the understanding of transformation mechanisms, contributing to the rational synthesis of high\u2010nuclearity nanoclusters.\n                  <\/jats:p>","DOI":"10.1002\/anie.202506971","type":"journal-article","created":{"date-parts":[[2025,4,16]],"date-time":"2025-04-16T22:09:32Z","timestamp":1744841372000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Solvent Induced Transformation of Homoleptic Alkynyl\u2010Protected Large Silver Nanoclusters"],"prefix":"10.1002","volume":"64","author":[{"given":"Lu\u2010Ming","family":"Zheng","sequence":"first","affiliation":[{"name":"Department of Chemistry Engineering Research Center of Advanced Rare Earth Materials (Ministry of Education) Tsinghua University  Beijing 100084 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhen\u2010Chao","family":"Long","sequence":"additional","affiliation":[{"name":"Department of Chemistry Engineering Research Center of Advanced Rare Earth Materials (Ministry of Education) Tsinghua University  Beijing 100084 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Feng","family":"Hu","sequence":"additional","affiliation":[{"name":"Department of Chemistry Engineering Research Center of Advanced Rare Earth Materials (Ministry of Education) Tsinghua University  Beijing 100084 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiangtao","family":"Chan","sequence":"additional","affiliation":[{"name":"Department of Chemistry Key Laboratory of Organic Optoelectronics and Molecular Engineering Tsinghua University  Beijing 100084 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wan\u2010Qi","family":"Shi","sequence":"additional","affiliation":[{"name":"Department of Chemistry Engineering Research Center of Advanced Rare Earth Materials (Ministry of Education) Tsinghua University  Beijing 100084 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ben","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Chemistry Engineering Research Center of Advanced Rare Earth Materials (Ministry of Education) Tsinghua University  Beijing 100084 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhaohui","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemistry Key Laboratory of Organic Optoelectronics and Molecular Engineering Tsinghua University  Beijing 100084 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Quan\u2010Ming","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemistry Engineering Research Center of Advanced Rare Earth Materials (Ministry of Education) Tsinghua University  Beijing 100084 P.R. 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