{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:30:43Z","timestamp":1786977043866,"version":"build-2736575974"},"reference-count":63,"publisher":"Wiley","issue":"33","license":[{"start":{"date-parts":[[2025,6,23]],"date-time":"2025-06-23T00:00:00Z","timestamp":1750636800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21901025"],"award-info":[{"award-number":["21901025"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["2024CDJXY010"],"award-info":[{"award-number":["2024CDJXY010"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["2024CDJQYJCYJ\u2010001"],"award-info":[{"award-number":["2024CDJQYJCYJ\u2010001"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100005230","name":"Natural Science Foundation of Chongqing","doi-asserted-by":"publisher","award":["CSTB2023NSCQ\u2010MSX0354"],"award-info":[{"award-number":["CSTB2023NSCQ\u2010MSX0354"]}],"id":[{"id":"10.13039\/501100005230","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,8,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The extreme similarity in electronic and steric reactivity among the C\u2500H bonds present on alkyl\u2010substituted aromatic rings presents a formidable challenge when it comes to achieving high selectivity during the\n                    <jats:italic>para<\/jats:italic>\n                    \u2010selective functionalization of these bonds. This article presents a unique study that delves into the\n                    <jats:italic>para<\/jats:italic>\n                    \u2010selective functionalization or dearomatization functionalization of benzene rings, achieved through the reaction of carbenes with allyl sulfoxides. Mechanistic investigations suggest that the transformation likely proceeds via an uncommon carbene\u2010mediated [4,5]\u2010rearrangement process.\n                  <\/jats:p>","DOI":"10.1002\/anie.202507149","type":"journal-article","created":{"date-parts":[[2025,6,17]],"date-time":"2025-06-17T04:21:05Z","timestamp":1750134065000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Selective Functionalization of Benzene Ring via Carbene\u2010Initiated [4,5]\u2010Rearrangement"],"prefix":"10.1002","volume":"64","author":[{"given":"Xuerong","family":"Wang","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering Chongqing University  Chongqing 401331 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chuang","family":"Mei","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Chongqing University  Chongqing 401331 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yulu","family":"Song","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Chongqing University  Chongqing 401331 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fengyi","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Chongqing University  Chongqing 401331 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongyan","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Chongqing University  Chongqing 401331 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yao","family":"Lei","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Chongqing University  Chongqing 401331 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5723-6514","authenticated-orcid":false,"given":"Jiarong","family":"Shi","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Chongqing University  Chongqing 401331 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,6,23]]},"reference":[{"key":"e_1_2_5_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00716K"},{"key":"e_1_2_5_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.201800203"},{"key":"e_1_2_5_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202001224"},{"key":"e_1_2_5_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1QO01636A"},{"key":"e_1_2_5_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-021-00300-6"},{"key":"e_1_2_5_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.6b00032"},{"key":"e_1_2_5_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-024-01194-5"},{"key":"e_1_2_5_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00220"},{"key":"e_1_2_5_9_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abd5992"},{"key":"e_1_2_5_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature11158"},{"key":"e_1_2_5_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature21418"},{"key":"e_1_2_5_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-022-05175-1"},{"key":"e_1_2_5_13_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1169975"},{"key":"e_1_2_5_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c12654"},{"key":"e_1_2_5_15_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aac9895"},{"key":"e_1_2_5_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00201K"},{"key":"e_1_2_5_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2020.213683"},{"key":"e_1_2_5_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201812116"},{"key":"e_1_2_5_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c04074"},{"key":"e_1_2_5_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b06793"},{"key":"e_1_2_5_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b04490"},{"key":"e_1_2_5_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.8b03871"},{"key":"e_1_2_5_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo00376a007"},{"key":"e_1_2_5_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)98888-9"},{"key":"e_1_2_5_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b00969"},{"key":"e_1_2_5_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201900434"},{"key":"e_1_2_5_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202212160"},{"key":"e_1_2_5_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00947a034"},{"key":"e_1_2_5_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00947a033"},{"key":"e_1_2_5_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/tcr.202200150"},{"key":"e_1_2_5_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201909019"},{"key":"e_1_2_5_32_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-32426-6"},{"key":"e_1_2_5_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c04389"},{"key":"e_1_2_5_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol501638x"},{"key":"e_1_2_5_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1OB02491D"},{"key":"e_1_2_5_36_1","doi-asserted-by":"publisher","DOI":"10.1055\/s-0036-1588971"},{"key":"e_1_2_5_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.7b03413"},{"key":"e_1_2_5_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2021.153258"},{"key":"e_1_2_5_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.202200441"},{"key":"e_1_2_5_40_1","doi-asserted-by":"publisher","DOI":"10.1111\/j.1365-2222.2009.03257.x"},{"key":"e_1_2_5_41_1","unstructured":"L.Xiu L.Du N.Wang D.Tan D.Zou D.Zhao K.Wang CN 104177331 A 2014."},{"key":"e_1_2_5_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/0223-5234(91)90009-C"},{"key":"e_1_2_5_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/0090-6980(87)90306-6"},{"key":"e_1_2_5_44_1","doi-asserted-by":"publisher","DOI":"10.1163\/156856003322699555"},{"key":"e_1_2_5_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2021.113530"},{"key":"e_1_2_5_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2009.12.005"},{"key":"e_1_2_5_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja055021d"},{"key":"e_1_2_5_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201607278"},{"key":"e_1_2_5_49_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2789"},{"key":"e_1_2_5_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00811"},{"key":"e_1_2_5_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00348"},{"key":"e_1_2_5_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00382"},{"key":"e_1_2_5_53_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00072B"},{"key":"e_1_2_5_54_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0cs00217h"},{"key":"e_1_2_5_55_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-50675-5"},{"key":"e_1_2_5_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202312856"},{"key":"e_1_2_5_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/ol006177f"},{"key":"e_1_2_5_58_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC00641F"},{"key":"e_1_2_5_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja206572w"},{"key":"e_1_2_5_60_1","doi-asserted-by":"publisher","DOI":"10.1055\/s-2003-37349"},{"key":"e_1_2_5_61_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-024-01207-3"},{"key":"e_1_2_5_62_1","unstructured":"Deposition Number(s) 2383808 (for3s) and 2383809 (for12) contain(s) the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum KarlsruheAccess Structures service."},{"key":"e_1_2_5_63_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c11119"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202507149","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,12,1]],"date-time":"2025-12-01T14:52:35Z","timestamp":1764600755000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202507149"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,6,23]]},"references-count":63,"journal-issue":{"issue":"33","published-print":{"date-parts":[[2025,8,11]]}},"alternative-id":["10.1002\/anie.202507149"],"URL":"https:\/\/doi.org\/10.1002\/anie.202507149","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,6,23]]},"assertion":[{"value":"2025-03-30","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-06-16","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-06-23","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202507149"}}