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However, the high activation energy for C\u2550O bonds (in both PET and CO\n                    <jats:sub>2<\/jats:sub>\n                    ) and the difficulty in regulating the reaction pathways restricted PET recovery efficiency. Here, we demonstrated the rational design of a single\u2010atom Cu catalyst for precisely catalyzing the hydrogenation of CO\n                    <jats:sub>2<\/jats:sub>\n                    to methanol and tandem PET upcycling to ethylene glycol (EG) and\n                    <jats:italic>p<\/jats:italic>\n                    \u2010xylene (PX). In the Cu\/UiO\u201066\u2010NH\n                    <jats:sub>2<\/jats:sub>\n                    \u2010A catalyst, Cu atoms are selectively anchored to the Zr\u2010oxo nodes of UiO\u201066\u2010NH\n                    <jats:sub>2<\/jats:sub>\n                    to form Cu\u2013O\u2013Zr sites. The Cu\u2013O\u2013Zr sites can effectively activate both CO\n                    <jats:sub>2<\/jats:sub>\n                    and H\n                    <jats:sub>2<\/jats:sub>\n                    by reducing the activation energy and accelerate the transformation of PET to dimethyl terephthalate (DMT), which is further hydro\u2010deoxygenated to yield PX. As a result, 20.4% CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion was obtained within 36\u00a0h, with 89.5% and 92.1% yields of PX and EG, respectively. Rapid and precise hydrogen spillover from Cu atoms to adsorbed reactants\/intermediates at the Cu\u2013O\u2013Zr sites also drives the reaction process.\n                  <\/jats:p>","DOI":"10.1002\/anie.202507309","type":"journal-article","created":{"date-parts":[[2025,5,19]],"date-time":"2025-05-19T08:55:40Z","timestamp":1747644940000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["Atomic Cu\u2013O\u2013Zr Sites for Highly Selective Production of\n                    <i>p<\/i>\n                    \u2010xylene from Tandem Upcycling of PET and CO\n                    <sub>2<\/sub>"],"prefix":"10.1002","volume":"64","author":[{"given":"Qizhuang","family":"Zou","sequence":"first","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Fuel Cell Technology School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510640 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tairen","family":"Long","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry College of Chemistry and Chemical Engineering Xiamen University  Xiamen 360015 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruiqi","family":"Fang","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Fuel Cell Technology School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510640 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Zhao","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Fuel Cell Technology School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510640 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fengliang","family":"Wang","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Fuel Cell Technology School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510640 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1527-551X","authenticated-orcid":false,"given":"Yingwei","family":"Li","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Fuel Cell Technology School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 510640 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