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However, they continue to face challenges such as limited cycle life and significant polarization caused by anode degradation, which is often overlooked and whose underlying mechanism remains unclear. This work revealed the anode failure mechanism, identifying a water\u2010triggered degradation process, which depletes active lithium content, and developed an atmosphere\u2010induced protective strategy. The degradation is triggered by trace water and sustained by the CO\n                    <jats:sub>2<\/jats:sub>\n                    component, which results in transforming active lithium into Li\n                    <jats:sub>2<\/jats:sub>\n                    CO\n                    <jats:sub>3<\/jats:sub>\n                    . Thus, a strategy was provided to respond to the water molecules brought by the semi\u2010hermetic system and high charging voltage. The protective layer was in situ polymerized and can interact with water molecules, leading to further polymerization, thereby inhibiting side reactions, significantly extending the battery's lifespan. The Li\u2013CO\n                    <jats:sub>2<\/jats:sub>\n                    batteries can achieve stable cycling exceeding 1000\u00a0h, more than twice the time compared to the unprotected case. This study revealed the fundamental mechanism of anode degradation in Li\u2013CO\n                    <jats:sub>2<\/jats:sub>\n                    batteries, providing a theoretical basis for the development of subsequent anode protection strategies. Additionally, it offers a viable method for anode protection in Li\u2013CO\n                    <jats:sub>2<\/jats:sub>\n                    batteries.\n                  <\/jats:p>","DOI":"10.1002\/anie.202507865","type":"journal-article","created":{"date-parts":[[2025,4,28]],"date-time":"2025-04-28T15:24:23Z","timestamp":1745853863000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["An Atmosphere\u2010Responsive Protective Strategy Based on Deciphering the Anode Degradation Mechanism in Li\u2013CO\n                    <sub>2<\/sub>\n                    Batteries"],"prefix":"10.1002","volume":"64","author":[{"given":"Yanze","family":"Song","sequence":"first","affiliation":[{"name":"Tsinghua Shenzhen International Graduate School Tsinghua University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haotian","family":"Qu","sequence":"additional","affiliation":[{"name":"Tsinghua Shenzhen International Graduate School Tsinghua University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinru","family":"Wu","sequence":"additional","affiliation":[{"name":"Tsinghua Shenzhen International Graduate School Tsinghua University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yingqi","family":"Liu","sequence":"additional","affiliation":[{"name":"Tsinghua Shenzhen International Graduate School Tsinghua University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bingyi","family":"Lu","sequence":"additional","affiliation":[{"name":"Tsinghua Shenzhen International Graduate School Tsinghua University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanli","family":"Chen","sequence":"additional","affiliation":[{"name":"Tsinghua Shenzhen International Graduate School Tsinghua University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Tao","sequence":"additional","affiliation":[{"name":"Tsinghua Shenzhen International Graduate School Tsinghua University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guangmin","family":"Zhou","sequence":"additional","affiliation":[{"name":"Tsinghua Shenzhen International Graduate School Tsinghua University  Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,5,12]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-021-04376-4"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abn7950"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-32471-1"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aas9793"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201908285"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0EE03058A"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8EE03417F"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2020.09.014"},{"key":"e_1_2_7_9_1","first-page":"22","volume":"32","author":"Mu X. 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