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Herein, we demonstrate an efficient CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010to\u2010methanol catalyst (PdCu\/PCN), consisting of ultrafine PdCu disordered nanoalloys anchored on polymeric carbon nitride (PCN) nanosheets. Prepared via a facile one\u2010pot co\u2010polymerization recipe, this strategy permits the in situ formation and integration of PdCu alloys during PCN synthesis, which ensures strong interfacial confinement and prevents the generation of oxide\u2010derived encapsulation overlayers, maximizing the exposure of active metal sites. Despite its ultralow metal loading (Pd: 0.18%, Cu: 0.16%), the catalyst achieves a high methanol production rate of 21.24\u00a0mmol g\n                    <jats:sub>metal<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    with 100% selectivity at 160\u00a0\u00b0C, together with outstanding reusability. Alloying Cu with Pd in a disordered nanoalloy structure modulates the CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation pathway toward methanol while lowering the energy barrier of the rate\u2010determining step. This work highlights the potential of PCN as a flexible metal\u2010free support for constructing active and durable catalysts for selective CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion through in situ alloy engineering.\n                  <\/jats:p>","DOI":"10.1002\/anie.202508611","type":"journal-article","created":{"date-parts":[[2025,9,29]],"date-time":"2025-09-29T10:32:41Z","timestamp":1759141961000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Ultralow\u2010Content PdCu Disordered Nanoalloys on Carbon Nitrides for Unity\u2010Selective CO\n                    <sub>2<\/sub>\n                    Hydrogenation to Methanol"],"prefix":"10.1002","volume":"64","author":[{"given":"Yuhan","family":"Wang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemistry for NBC Hazards Protection College of Chemistry Fuzhou University  Fuzhou 350116 China"},{"name":"State 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