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However, most existing light\u2010driven micro\/nanomotors, which are typically fabricated from inorganic semiconductors, suffer from limited visible\u2010light absorption and inadequate control over 3D motion. Polymeric semiconductors, as emerging photocatalytic materials, feature narrow bandgaps, tunable band structures, and the potential for rational molecular design to optimize activity. This study introduces phenolic resins as efficient semiconductor photocatalysts, establishing a novel platform for constructing light\u2010driven nanomotors. Among them, the\n                    <jats:italic>m<\/jats:italic>\n                    \u2010aminophenol\u2010formaldehyde resin nanomotor, synthesized via hydrothermal methods, exhibits exceptional mobility due to its efficient photoelectric conversion and charge transfer behavior. Its outstanding photoelectrochemical properties originate from a benzoxazine\u2010quinoid structure with a low HOMO\u2013LUMO gap (1.90\u00a0eV). These nanomotors feature broad\u2010spectrum light absorption and can respond to various external stimuli, including light intensity, wavelength, and H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    concentration, enabling precise control over in\u2010plane and vertical motion with adjustable speed and directionality. As a proof of concept, the nanomotors demonstrate superior photodynamic inactivation of\n                    <jats:italic>Karenia mikimotoi<\/jats:italic>\n                    under visible light exposure, surpassing TiO\n                    <jats:sub>2<\/jats:sub>\n                    nanoparticles in antimicrobial efficiency. This work explores the relationship between molecular structure, photocatalytic performance, and motion behavior, providing instructive insights for designing light\u2010driven nanomotors with advanced motion manipulation.\n                  <\/jats:p>","DOI":"10.1002\/anie.202508705","type":"journal-article","created":{"date-parts":[[2025,7,30]],"date-time":"2025-07-30T06:29:37Z","timestamp":1753856977000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Molecular\u2010Level Design of Polymeric Semiconductor Nanomotors with Multichannel Sensitive 3D Motion for Microorganism Inactivation"],"prefix":"10.1002","volume":"64","author":[{"given":"Tianyi","family":"Liu","sequence":"first","affiliation":[{"name":"College of Materials Science and Chemical Engineering Harbin Engineering University  Harbin Heilongjiang 150001 P.R. 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