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Herein, we reveal that modifying the skeleton of D\u2013A dyads from U\u2010shaped to V\u2010shaped configurations yields\n                    <jats:sup>3<\/jats:sup>\n                    CT\u2010RTP with both long\n                    <jats:italic>\u03c4<\/jats:italic>\n                    <jats:sub>Ph<\/jats:sub>\n                    (150\u2013220\u00a0ms) and high  (13%\u201325%). This improvement stems from preserving a substantial degree of forbiddenness in the radiative transition process of the compound while simultaneously increasing its D\u2013A dihedral angle, which can promote more efficient spin\u2010orbit coupling and thus more rapid intersystem crossing. Additionally, augmenting the framework rigidity of a V\u2010shaped D\u2013A dyad can potentially reduce the non\u2010radiative transition rate constant of triplet excitons (\n                    <jats:italic>k<\/jats:italic>\n                    <jats:sub>nr,T<\/jats:sub>\n                    ), thereby facilitating the attainment of long\n                    <jats:italic>\u03c4<\/jats:italic>\n                    <jats:sub>Ph<\/jats:sub>\n                    and high .\n                  <\/jats:p>","DOI":"10.1002\/anie.202508776","type":"journal-article","created":{"date-parts":[[2025,7,31]],"date-time":"2025-07-31T11:45:57Z","timestamp":1753962357000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Achieving Charge\u2010Transfer\u2010Featured Organic Room\u2010Temperature Phosphorescence with Combined High Efficiency and Long Lifetime via V\u2010Shaped D\u2013A Dyads"],"prefix":"10.1002","volume":"64","author":[{"given":"Kuan","family":"Chen","sequence":"first","affiliation":[{"name":"Key Laboratory of Green Chemistry and Technology (Ministry of Education), College of Chemistry Sichuan University  Chengdu 610064 China"},{"name":"Werlchem New Materials Co., Ltd  Chongqing 401121 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Binhao","family":"Li","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry and Technology (Ministry of Education), College of Chemistry Sichuan University  Chengdu 610064 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chuanhao","family":"Liu","sequence":"additional","affiliation":[{"name":"Analytical &amp; Testing Center Sichuan University  Chengdu 610064 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanju","family":"Luo","sequence":"additional","affiliation":[{"name":"Analytical &amp; Testing Center Sichuan University  Chengdu 610064 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kaixin","family":"Yu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry and Technology (Ministry of Education), College of Chemistry Sichuan University  Chengdu 610064 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengjiao","family":"Jia","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry and Technology (Ministry of Education), College of Chemistry Sichuan University  Chengdu 610064 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan","family":"Huang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry and Technology (Ministry of Education), College of Chemistry Sichuan University  Chengdu 610064 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1733-4061","authenticated-orcid":false,"given":"Zhiyun","family":"Lu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Green Chemistry and Technology (Ministry of Education), College of Chemistry Sichuan University  Chengdu 610064 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,7,31]]},"reference":[{"key":"e_1_2_5_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TC00738B"},{"key":"e_1_2_5_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202312534"},{"key":"e_1_2_5_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CC01910A"},{"key":"e_1_2_5_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202413896"},{"key":"e_1_2_5_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.2c01614"},{"key":"e_1_2_5_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202207161"},{"key":"e_1_2_5_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201008004"},{"key":"e_1_2_5_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202302624"},{"key":"e_1_2_5_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202301874"},{"key":"e_1_2_5_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202201820"},{"key":"e_1_2_5_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202204415"},{"key":"e_1_2_5_12_1","author":"Wang K.","year":"2025","journal-title":"Angew. 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These data are provided free of charge by the joint Cambridge Crystallographic Data Centre viawww.ccdc.cam.ac.uk\/structures\/."},{"key":"e_1_2_5_20_1","unstructured":"The deposition numbers CCDC2444840(for V\u20101) contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre viawww.ccdc.cam.ac.uk\/structures\/."},{"key":"e_1_2_5_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-021-01132-x"},{"key":"e_1_2_5_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202009439"},{"key":"e_1_2_5_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00245a014"},{"key":"e_1_2_5_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja100936w"},{"key":"e_1_2_5_25_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-32029-1"},{"key":"e_1_2_5_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.201700116"},{"key":"e_1_2_5_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/agt2.468"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202508776","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202508776","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202508776","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,10]],"date-time":"2026-10-10T15:49:45Z","timestamp":1791647385000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202508776"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,7,31]]},"references-count":27,"journal-issue":{"issue":"38","published-print":{"date-parts":[[2025,9,15]]}},"alternative-id":["10.1002\/anie.202508776"],"URL":"https:\/\/doi.org\/10.1002\/anie.202508776","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,7,31]]},"assertion":[{"value":"2025-04-21","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-07-23","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-07-31","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202508776"}}