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Herein, we report the synthesis of two PAHs through the fusion of\n                    <jats:italic>N<\/jats:italic>\n                    \u2010arylcarbazole on one side of a dibenzophenalene precursor edged with a pristine zigzag nitrogen (N)\u2013boron (B)\u2013nitrogen (N) unit. Their unique planar\u2010negatively curved molecular skeletons were revealed by X\u2010ray single crystal structure analysis. Fusing another benzene ring at the terminal positions of such kinds of PAH molecules resulted in a more contorted structure, which led to the successive reversible electrochemical behaviors, stronger hydrophilicity, and better photogenerated charge generation and separation as evidenced by experimental and theoretical data. Upon visible\u2010light activation, the as\u2010prepared PAHs showed a curvature\u2010strengthened photocatalytic activity of hydrogen peroxide (H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    ) production (yield: up to 6696\u00a0\u00b5mol h\n                    <jats:sup>\u22121<\/jats:sup>\n                    g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) with good recyclability and reusability. Finally, the femtosecond transient absorption spectra (fs\u2010TAS) indicate that the more curved structure Nap\u2010NBN\u2010PAH has more photogenerated charges and a longer excited state lifetime, which is consistent with better photocatalytic performance.\n                  <\/jats:p>","DOI":"10.1002\/anie.202508785","type":"journal-article","created":{"date-parts":[[2025,9,25]],"date-time":"2025-09-25T10:13:43Z","timestamp":1758795223000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Polycyclic Heteroaromatics with Planar\u2010Curved Hybrid Skeletons for High\u2010Performance Photocatalytic Hydrogen Peroxide Evolution"],"prefix":"10.1002","volume":"64","author":[{"given":"Yang","family":"Jiao","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering State Key Laboratory of Synergistic Chem\u2010Bio Synthesis Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 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