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We address this challenge through the strategic synthesis of metal\u2010free conjugated porous aromatic frameworks (PAFs), PAF\u2010332\u2010DCM, to enhance the NIR absorption capabilities, achieving a CO production rate of ~74.7\u00a0\u00b5mol\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    in gas\u2010solid phase CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction, surpassing typical NIR\u2010responsive catalysts. Meanwhile, PAF\u2010332\u2010DCM can obtain a CO production rate of 344.1\u00a0\u00b5mol\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    in full\u2010spectrum irradiated CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction. Infrared thermography reveals that the non\u2010radiative attenuation of PAF\u2010332\u2010DCM leads to high photothermal temperature under NIR irradiation, which accounts for its reduction performance. Mechanistic studies combining fs\u2010TA spectroscopy and in situ infrared characterization elucidate the photocatalytic pathway and intermediate formation. This result indicates that PAF\u2010332\u2010DCM can be a promising metal\u2010free catalyst for practical solar\u2010driven CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion.\n                  <\/jats:p>","DOI":"10.1002\/anie.202508924","type":"journal-article","created":{"date-parts":[[2025,7,1]],"date-time":"2025-07-01T22:10:48Z","timestamp":1751407848000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":32,"title":["Near\u2010Infrared Light Catalysis of Carbon Dioxide Reduction by Conjugated Porous Aromatic Frameworks"],"prefix":"10.1002","volume":"64","author":[{"given":"Zihao","family":"Wang","sequence":"first","affiliation":[{"name":"Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education Faculty of Chemistry, Northeast Normal University  Changchun Jilin 130024 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