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Consequently, a new type of multi\u2010color STADF polymeric materials GPs@C[3]A were constructed by host\u2013guest complexation between calix[3]acridan (C[3]A) and different guest\u2010linked polymers (GPs). Interestingly, by adjusting the added molar proportion of C[3]A, multi\u2010color TADF property of GPs@C[3]A could also be easily tuned. Notably, when a 20% molar ratio of C[3]A was added, GP1@C[3]A exhibited white luminescence. Especially, by using the high selectivity of C[3]A toward benzene and its differential binding affinities for acceptor guests versus benzene, rapid detection of trace benzene vapor was achieved in few seconds with the naked eyes. The limit of detection concentrations for benzene reached 3.5\u00a0mg L\n                    <jats:sup>\u22121<\/jats:sup>\n                    , indicating GPs@C[3]A could be used as an excellent sensor for rapid detection of benzene at trace level. Furthermore, GP1@C[3]A could also be fabricated into a visualized and convenient paper\u2010based sensor strip for detecting benzene in cyclohexane. This work offers an innovative idea for the application of STADF materials in detection, and also addresses the key challenge of simultaneously improving sensitivity, selectivity and visualization in benzene detection.\n                  <\/jats:p>","DOI":"10.1002\/anie.202508987","type":"journal-article","created":{"date-parts":[[2025,5,7]],"date-time":"2025-05-07T06:55:35Z","timestamp":1746600935000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Supramolecular TADF Materials from Calix[3]Acridan and Guest\u2010Linked Polymers for Rapid and Visual Detection of Trace Benzene"],"prefix":"10.1002","volume":"64","author":[{"given":"Ying","family":"Han","sequence":"first","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Molecular Recognition and Function Institute of Chemistry Chinese Academy of Sciences  Beijing 100190 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kui\u2010Zhu","family":"Song","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu\u2010Jie","family":"Long","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Molecular Recognition and Function Institute of Chemistry Chinese Academy of Sciences  Beijing 100190 China"},{"name":"School of Chemical Sciences University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei\u2010Chen","family":"Guo","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Molecular Recognition and Function Institute of Chemistry Chinese Academy of Sciences  Beijing 100190 China"},{"name":"School of Chemical Sciences University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ming\u2010Jun","family":"Ji","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Molecular Recognition and Function Institute of Chemistry Chinese Academy of Sciences  Beijing 100190 China"},{"name":"School of Chemical Sciences University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao\u2010Ni","family":"Han","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Molecular Recognition and Function Institute of Chemistry Chinese Academy of Sciences  Beijing 100190 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4347-1406","authenticated-orcid":false,"given":"Chuan\u2010Feng","family":"Chen","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Molecular Recognition and Function Institute of Chemistry Chinese Academy of Sciences  Beijing 100190 China"},{"name":"School of Chemical Sciences University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,5,20]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/nphoton.2012.31"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00368K"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.7b18318"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.4737006"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201405062"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201904427"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b10257"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/agt2.4"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11426-020-9750-9"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/marc.202200064"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202304103"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b07156"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201902264"},{"key":"e_1_2_7_14_1","first-page":"1","volume":"68","author":"Li S.","year":"2025","journal-title":"Sci. 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