{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T01:27:09Z","timestamp":1792027629704,"version":"4.4.0"},"reference-count":55,"publisher":"Wiley","issue":"33","license":[{"start":{"date-parts":[[2025,7,16]],"date-time":"2025-07-16T00:00:00Z","timestamp":1752624000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["SFB1459 Intelligent Matter"],"award-info":[{"award-number":["SFB1459 Intelligent Matter"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,8,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Supramolecular polymorphism has recently emerged as a powerful concept, enabling a single chemical entity to form distinct, stable assemblies in solution with diverse morphological, photophysical, and electronic properties. Despite this progress, the interplay between supramolecular polymorphism and chirality remains unexplored. Herein, we harness supramolecular polymorphism to control the amplification of asymmetry in supramolecular polymerization (SP). For this purpose, we designed two Pt(II) complexes bearing\n                    <jats:italic>\u03c0<\/jats:italic>\n                    \u2010extended ligands and\n                    <jats:italic>S<\/jats:italic>\n                    \u2010 or\n                    <jats:italic>R<\/jats:italic>\n                    \u2010chiral side chains (compounds\n                    <jats:bold>\n                      (\n                      <jats:italic>S<\/jats:italic>\n                      )\u20101\n                    <\/jats:bold>\n                    and\n                    <jats:bold>\n                      (\n                      <jats:italic>R<\/jats:italic>\n                      )\u20101\n                    <\/jats:bold>\n                    ) that self\u2010assemble into two distinct supramolecular polymorphs in methylcyclohexane: nonemissive short fibers with parallel molecular packing (\n                    <jats:bold>AggI<\/jats:bold>\n                    ) and thermodynamically more stable helical fibers with a rotationally offset stacking, closer Pt\u22efPt contacts, and weak\n                    <jats:sup>3<\/jats:sup>\n                    MMLCT luminescence (\n                    <jats:bold>AggII<\/jats:bold>\n                    ). These polymorphs exhibit markedly different amplification of asymmetry in majority rules (\n                    <jats:italic>MR<\/jats:italic>\n                    ) and sergeants\u2010and\u2010soldiers (\n                    <jats:italic>SaS<\/jats:italic>\n                    ) studies, with the thermodynamic polymorph displaying superior performance. Ultimately, coassembly studies between the achiral model compound\n                    <jats:bold>2<\/jats:bold>\n                    \u2014which exhibits strong\n                    <jats:sup>3<\/jats:sup>\n                    MMLCT emission in the assembled state\u2014and the chiral but weakly emissive\n                    <jats:bold>AggII<\/jats:bold>\n                    reveal a synergistic communication between chirality and luminescence, culminating in the emergence of circularly polarized luminescence (CPL). This study broadens the scope of supramolecular polymorphism and expands the design toolbox for adaptive supramolecular materials with emergent and synergistic functionalities.\n                  <\/jats:p>","DOI":"10.1002\/anie.202509031","type":"journal-article","created":{"date-parts":[[2025,5,19]],"date-time":"2025-05-19T06:36:04Z","timestamp":1747636564000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":30,"title":["Controlling Asymmetry Amplification Through Supramolecular Polymorphism"],"prefix":"10.1002","volume":"64","author":[{"given":"Camila","family":"Monta\u00f1ez\u2010Moyano","sequence":"first","affiliation":[{"name":"Organisch\u2010Chemisches Institut Universit\u00e4t M\u00fcnster  Corrensstra\u00dfe 36 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuncong","family":"Xue","sequence":"additional","affiliation":[{"name":"Organisch\u2010Chemisches Institut Universit\u00e4t M\u00fcnster  Corrensstra\u00dfe 36 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mar\u00eda Victoria","family":"Cappellari","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische und Analytische Chemie, CiMiC, SoN and CeNTech Universit\u00e4t M\u00fcnster 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alejandro","family":"Mart\u00ednez\u2010Manjarr\u00e9s","sequence":"additional","affiliation":[{"name":"Organisch\u2010Chemisches Institut Universit\u00e4t M\u00fcnster  Corrensstra\u00dfe 36 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lorenz","family":"Borsdorf","sequence":"additional","affiliation":[{"name":"Organisch\u2010Chemisches Institut Universit\u00e4t M\u00fcnster  Corrensstra\u00dfe 36 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cristian A.","family":"Strassert","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische und Analytische Chemie, CiMiC, SoN and CeNTech Universit\u00e4t M\u00fcnster 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6155-8671","authenticated-orcid":false,"given":"Gustavo","family":"Fern\u00e1ndez","sequence":"additional","affiliation":[{"name":"Organisch\u2010Chemisches Institut Universit\u00e4t M\u00fcnster  Corrensstra\u00dfe 36 48149 M\u00fcnster Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,7,16]]},"reference":[{"key":"e_1_2_7_1_1","first-page":"675","volume":"2","author":"Bernstein J.","year":"2002","journal-title":"Int. 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