{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T13:23:46Z","timestamp":1790774626585,"version":"4.1.0"},"reference-count":68,"publisher":"Wiley","issue":"36","license":[{"start":{"date-parts":[[2025,7,16]],"date-time":"2025-07-16T00:00:00Z","timestamp":1752624000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,7,16]],"date-time":"2025-07-16T00:00:00Z","timestamp":1752624000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22279143"],"award-info":[{"award-number":["22279143"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,9,1]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Photocatalytic reduction of carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    ) provides a promising strategy for producing high\u2010value chemicals and fuels. However, developing high\u2010performance photocatalysts for CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction remains a great challenge due to the poor stability of reaction intermediates. Herein, we present an anionic coordination strategy to facilitate the stabilization of intermediates by constructing halogen\u2010coordinated metal\u2010organic cages (MOCs) (Ni\n                    <jats:sub>8<\/jats:sub>\n                    L\n                    <jats:sub>12<\/jats:sub>\n                    X\n                    <jats:sub>4<\/jats:sub>\n                    , X = Cl, Br, I). Theoretical calculations show that the formation of *COOH intermediate is the rate\u2010limiting step and halogen coordination effectively regulates the energy barrier for this reaction. Notably, iodide anions significantly reduce the energy gap between the Ni\n                    <jats:italic>d<\/jats:italic>\n                    and iodide\n                    <jats:italic>p<\/jats:italic>\n                    orbitals, enhancing electron transfer from the Ni center to adsorbed CO\n                    <jats:sub>2<\/jats:sub>\n                    and promoting the production of *COOH. As a result, Ni\n                    <jats:sub>8<\/jats:sub>\n                    L\n                    <jats:sub>12<\/jats:sub>\n                    I\n                    <jats:sub>4<\/jats:sub>\n                    demonstrates superior performance with a CO production rate of 2680.23\u00a0\n                    <jats:italic>\u00b5<\/jats:italic>\n                    mol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    and 95% selectivity, outperforming Cl\u2010 and Br\u2010coordinated Ni MOC by 200\u2010 and 5\u2010fold, respectively. This work opens a new coordination engineering strategy for fabricating efficient photocatalysts for CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction.\n                  <\/jats:p>","DOI":"10.1002\/anie.202509280","type":"journal-article","created":{"date-parts":[[2025,7,2]],"date-time":"2025-07-02T09:56:43Z","timestamp":1751450203000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["Anionic Coordination\u2010Regulated Metal\u2010Organic Cages for Efficient CO\n                    <sub>2<\/sub>\n                    Photoreduction"],"prefix":"10.1002","volume":"64","author":[{"given":"Linjing","family":"Huang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the structure of Matter Chinese Academy of Sciences  Fuzhou 350002 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liyang","family":"Qin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the structure of Matter Chinese Academy of Sciences  Fuzhou 350002 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sijie","family":"Wan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology  Wuhan 430070 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yayu","family":"Yan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the structure of Matter Chinese Academy of Sciences  Fuzhou 350002 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shaowen","family":"Cao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology  Wuhan 430070 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the structure of Matter Chinese Academy of Sciences  Fuzhou 350002 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7858-0047","authenticated-orcid":false,"given":"Tianhua","family":"Zhou","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the structure of Matter Chinese Academy of Sciences  Fuzhou 350002 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,7,16]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202403153"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2024.05.002"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202405825"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202317341"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202401562"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c12073"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202402070"},{"key":"e_1_2_7_8_1","author":"Xu M.","year":"2025","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c00432"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-94-009-7040-3_3"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0920-5861(01)00453-9"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202316080"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202319313"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3SC06059D"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202412777"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202418269"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.4c00129"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-023-01065-5"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CS00767G"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c16538"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-57742-5"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c08510"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CC00532H"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202310061"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c04289"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c14254"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202308505"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c10734"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2025.01.492"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-57822-6"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cjsc.2022.100010"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cjsc.2023.100090"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c18358"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cjsc.2024.100320"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201905869"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202305719"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202423018"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201610607"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.024.202404675"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202011068"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c01974"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jtice.2025.106134"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja4092984"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c00750"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c06676"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202425668"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c06530"},{"key":"e_1_2_7_48_1","author":"Mohata S.","year":"2025","journal-title":"Chem. Soc. Rev."},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.8b00062"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.9b09634"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.6b00540"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-025-01291-z"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-55891-1"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-36779-4"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c10090"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202423859"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b09705"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202201721"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201900546"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c06113"},{"key":"e_1_2_7_61_1","author":"Geng W.","year":"2025","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202500269"},{"key":"e_1_2_7_63_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2024.215997"},{"key":"e_1_2_7_64_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202411794"},{"key":"e_1_2_7_65_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c08953"},{"key":"e_1_2_7_66_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c04185"},{"key":"e_1_2_7_67_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202412965"},{"key":"e_1_2_7_68_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c01598"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202509280","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202509280","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202509280","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T16:23:26Z","timestamp":1784305406000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202509280"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,7,16]]},"references-count":68,"journal-issue":{"issue":"36","published-print":{"date-parts":[[2025,9,1]]}},"alternative-id":["10.1002\/anie.202509280"],"URL":"https:\/\/doi.org\/10.1002\/anie.202509280","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,7,16]]},"assertion":[{"value":"2025-04-27","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-07-02","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-07-16","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202509280"}}