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However, the efficient adsorption and speedy reaction of reactants following the specific mechanism in a favorable way is still a challenge for enhancing catalysis. Herein, we propose the strategy aimed at adjusting electronic properties of Ce\u2010O\n                    <jats:sub>v<\/jats:sub>\n                    \u2010W acid\u2013base pairs through constructing oxygen vacancies on Ce\/WO\n                    <jats:sub>x<\/jats:sub>\n                    , thereby fostering SCR activity. Experimental and theoretical results reveal that Ce\u2010O\n                    <jats:sub>v<\/jats:sub>\n                    \u2010W acid\u2013base pairs not only provide more Ce\n                    <jats:sup>3+<\/jats:sup>\n                    sites for promoting the reactivity of adsorbed NO, but also accelerate the reaction between NH\n                    <jats:sub>3<\/jats:sub>\n                    and gaseous NO owing to the generation of W\n                    <jats:sup>5+<\/jats:sup>\n                    species with superior surface acidity, which enhance Langmuir\u2013Hinshelwood and Eley\u2013Rideal mechanisms, respectively. Consequently, the designed catalysts achieve over 90% NO\n                    <jats:sub>x<\/jats:sub>\n                    conversion above 250 \u00b0C and exhibit higher activity than normal Ce\/WO\n                    <jats:sub>3<\/jats:sub>\n                    and V\/W\u2010TiO\n                    <jats:sub>2<\/jats:sub>\n                    commercial catalysts, with anti\u2010poisoning of SO\n                    <jats:sub>2<\/jats:sub>\n                    and H\n                    <jats:sub>2<\/jats:sub>\n                    O under harsh working conditions, expecting to provide the guidance for promoting de\u2010NO\n                    <jats:sub>x<\/jats:sub>\n                    industrial application.\n                  <\/jats:p>","DOI":"10.1002\/anie.202509362","type":"journal-article","created":{"date-parts":[[2025,7,8]],"date-time":"2025-07-08T10:30:27Z","timestamp":1751970627000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":29,"title":["Atomic\u2010Level Design of Acid\u2013Base Pairs in Oxides for Selective Catalytic Reduction of Nitrogen Oxides with Ammonia"],"prefix":"10.1002","volume":"64","author":[{"given":"Guoquan","family":"Liu","sequence":"first","affiliation":[{"name":"MOE Key Laboratory of Pollution Processes and Environmental Criteria, Tianjin Key Laboratory of Environmental Remediation and Pollution Control, College of Environmental Science and Engineering Nankai University  Tianjin 300350 P.R. 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