{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T19:08:26Z","timestamp":1792177706468,"version":"4.4.0"},"reference-count":52,"publisher":"Wiley","issue":"37","license":[{"start":{"date-parts":[[2026,7,24]],"date-time":"2026-07-24T00:00:00Z","timestamp":1784851200000},"content-version":"am","delay-in-days":365,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#am"},{"start":{"date-parts":[[2025,7,24]],"date-time":"2025-07-24T00:00:00Z","timestamp":1753315200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["CHE 2350218"],"award-info":[{"award-number":["CHE 2350218"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,9,8]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Reaction of Tl(OTf) with 2 equiv of bis(diisopropylamino)cyclopropenylidene (BAC) in THF results in formation of [Tl(BAC)\n                    <jats:sub>2<\/jats:sub>\n                    (OTf)] (\n                    <jats:bold>1<\/jats:bold>\n                    ) in moderate yields. Subsequent reaction of\n                    <jats:bold>1<\/jats:bold>\n                    with [K][H\n                    <jats:sub>2<\/jats:sub>\n                    \u20109\u2010BBN] ([H\n                    <jats:sub>2<\/jats:sub>\n                    \u20109\u2010BBN]\n                    <jats:sup>\u2212<\/jats:sup>\n                    \u00a0=\u00a0dihydrido 9\u2010boratabicyclo[3.3.1]nonane) in THF results in formation of [Tl(BAC)(\u03bc\u2010H\n                    <jats:sub>2<\/jats:sub>\n                    \u20109\u2010BBN)]\n                    <jats:sub>2<\/jats:sub>\n                    (\n                    <jats:bold>3<\/jats:bold>\n                    ), also in moderate yield. Complex\n                    <jats:bold>3<\/jats:bold>\n                    is the first reported thallium borohydride. We attribute its thermal stability to the strong donor ability of the BAC co\u2010ligand. Both\n                    <jats:bold>1<\/jats:bold>\n                    and\n                    <jats:bold>3<\/jats:bold>\n                    exhibit trigonal pyramidal geometries about Tl\n                    <jats:sup>+<\/jats:sup>\n                    in the solid\u2010state, indicative of the presence of stereochemically active lone pairs. The hydride environment in\n                    <jats:bold>3<\/jats:bold>\n                    is calculated to exhibit a 3.9\u00a0ppm downfield shift attributed to spin\u2010orbit effects from the adjacent Tl center.\n                  <\/jats:p>","DOI":"10.1002\/anie.202509732","type":"journal-article","created":{"date-parts":[[2025,7,25]],"date-time":"2025-07-25T06:58:53Z","timestamp":1753426733000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Spin\u2010Orbit Effects in a Thallium Borohydride Stabilized by Coordination to Bis(diisopropylamino)Cyclopropenylidene (BAC)"],"prefix":"10.1002","volume":"64","author":[{"given":"Thien H.","family":"Nguyen","sequence":"first","affiliation":[{"name":"Department of Chemistry and Biochemistry University of California, Santa Barbara  Santa Barbara CA 93106 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaojuan","family":"Yu","sequence":"additional","affiliation":[{"name":"Department of Chemistry University at Buffalo, State University of New York  Buffalo NY 14260 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guang","family":"Wu","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry University of California, Santa Barbara  Santa Barbara CA 93106 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jochen","family":"Autschbach","sequence":"additional","affiliation":[{"name":"Department of Chemistry University at Buffalo, State University of New York  Buffalo NY 14260 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4370-1424","authenticated-orcid":false,"given":"Trevor W.","family":"Hayton","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry University of California, Santa Barbara  Santa Barbara CA 93106 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,7,24]]},"reference":[{"key":"e_1_2_6_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.toxrep.2023.05.003"},{"key":"e_1_2_6_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.bioconjchem.2c00284"},{"key":"e_1_2_6_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2DT01074G"},{"key":"e_1_2_6_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.3c01050"},{"key":"e_1_2_6_5_1","unstructured":"Data taken from a search of the Cambridge Structural Database (CSD) Version 5.45 (April 2024 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covalent interaction energy of one BAC with the remaining [Tl2(\u03bc\u2010H2\u20109\u2010BBN)2(BAC)] fragment was calculated (scalar ZORA\/PBE restrained crystal structures) to be \u201026\u00a0kcal\/mol (see SI for full computational details)."}],"container-title":["Angewandte Chemie International 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