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Chirality, a fundamental characteristic governing biological recognition and signal transduction, remains underexplored in stannate clusters compared to extensively studied precious metal clusters. Herein, three enantiomeric pairs of chiral tin\u2010oxo clusters were constructed using axially chiral 1,1\u2032\u2010bi\u20102\u2010naphthol (BINOL) ligands. Structural analyses revealed supramolecular helical assemblies mediated by directional C\u2500H\u00b7\u00b7\u00b7\u03c0 interactions, while circular dichroism (CD) spectroscopy confirmed their intrinsic chirality. Through in situ doping engineering, non\u2010chiral fluorophores with distinct emission profiles were incorporated during chiral cluster crystallization, yielding composite materials exhibiting circularly polarized luminescence (CPL). The optimized system achieved a maximum dissymmetry factor (\n                    <jats:italic>g<\/jats:italic>\n                    <jats:sub>lum<\/jats:sub>\n                    ) of 1.5\u00a0\u00d7\u00a010\n                    <jats:sup>\u22122<\/jats:sup>\n                    . Mechanistic studies established that the spiral packing of the tin\u2010oxo clusters facilitates stereochemical information transfer to the dyes via the spatial confinement effect. This supramolecular chirality induction paradigm offers new insights into the rational design of multifunctional optical materials.\n                  <\/jats:p>","DOI":"10.1002\/anie.202509996","type":"journal-article","created":{"date-parts":[[2025,7,15]],"date-time":"2025-07-15T08:00:09Z","timestamp":1752566409000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Chiral Tin\u2010Oxo Cluster Matrices with Fluorophore Embedment for Multichromatic Circularly Polarized Luminescence"],"prefix":"10.1002","volume":"64","author":[{"given":"Gui\u2010Xin","family":"Yan","sequence":"first","affiliation":[{"name":"State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 China"},{"name":"College of Chemistry Fuzhou University  Fuzhou Fujian 350108 China"},{"name":"Fujian College University of Chinese Academy of Sciences  Fuzhou Fujian 350002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Er\u2010Xia","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 China"},{"name":"Fujian College University of Chinese Academy of Sciences  Fuzhou Fujian 350002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jin\u2010Xia","family":"Yang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7723-3676","authenticated-orcid":false,"given":"Qipu","family":"Lin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 China"},{"name":"Fujian College University of Chinese Academy of Sciences  Fuzhou Fujian 350002 China"},{"name":"University of Chinese Academy of Sciences  Beijing 100049 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Numbers2403433 (for Sn6L6\u2010R\u20141R) 2403434 (for Sn6L6\u2010S\u20141S) 2403435 (for Sn6L4\u2010R\u20142R) 2403436 (for Sn6L4\u2010S\u20142S) 2443855 (for Sn3Pb3IL6\u2010R\u20143R) 2443856 (for Sn3Pb3IL6\u2010S\u20143S)contain(s) the supplementary crystallographic data for this paper. These data are provided free of charge by the Cambridge Crystallographic Data CentreAccess Structures service."},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c09245"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202509996","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202509996","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202509996","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T16:24:56Z","timestamp":1784305496000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202509996"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,7,17]]},"references-count":33,"journal-issue":{"issue":"36","published-print":{"date-parts":[[2025,9,1]]}},"alternative-id":["10.1002\/anie.202509996"],"URL":"https:\/\/doi.org\/10.1002\/anie.202509996","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,7,17]]},"assertion":[{"value":"2025-05-06","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-07-10","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-07-17","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202509996"}}