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Therefore, the development of efficient EOR electrocatalysts has to target optimized redox properties. Herein, a Ni\n                    <jats:sup>0<\/jats:sup>\n                    \/Ni(OH)\n                    <jats:sub>2<\/jats:sub>\n                    heterostructure was synthesized by inducing a shift from hydrophilic to hydrophobic properties on the electrode surface during electrochemical deposition. The electrocatalyst enabled a current density of 573.7\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at 1.37\u00a0V versus RHE for EOR with a solar\u2010to\u2010hydrogen conversion efficiency of 14.4% when coupled to a commercial solar panel. Experimental and theoretical results disclosed that the incorporation of Ni\n                    <jats:sup>0<\/jats:sup>\n                    facilitates the ethanol to acetate kinetics through enhanced Ni\n                    <jats:sup>2+<\/jats:sup>\n                    to Ni\n                    <jats:sup>3+<\/jats:sup>\n                    conversion. The strategy, combining hydrogen production with the synthesis of value\u2010added products, enhances economic viability compared to conventional water electrolysis, underscoring its promise for practical implementation.\n                  <\/jats:p>","DOI":"10.1002\/anie.202510285","type":"journal-article","created":{"date-parts":[[2025,8,4]],"date-time":"2025-08-04T09:30:47Z","timestamp":1754299847000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":25,"title":["Metallic Ni as Electron Acceptor Modulates the Redox of Catalytic Centers at Activated Ni\n                    <sup>0<\/sup>\n                    \/Ni(OH)\n                    <sub>2<\/sub>\n                    Heterojunctions for Efficient Ethanol Electrooxidation"],"prefix":"10.1002","volume":"64","author":[{"given":"Ruixing","family":"Du","sequence":"first","affiliation":[{"name":"State Key Laboratory of Materials\u2010Oriented Chemical Engineering, College of 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