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In this work, we present a reproducible, room\u2010temperature reaction on a diiron bis\u2010cyclopentadienyl platform, providing access to a class of four substituted ferrabenzenes (\n                    <jats:bold>5a\u2010c<\/jats:bold>\n                    ), stabilized by \u03b7\n                    <jats:sup>6<\/jats:sup>\n                    \u2010coordination to a second iron fragment. This synthesis involves a one\u2010pot double C\u2500C coupling of iminium, carbene (from a diazo compound), and carbon monoxide moieties, yielding ferra\u2010cyclohexadienone derivatives (\n                    <jats:bold>4a\u2010c<\/jats:bold>\n                    ), followed by\n                    <jats:italic>O<\/jats:italic>\n                    \u2010alkylation with alkyl triflates. Experimental and computational studies enabled the proposal of a plausible reaction mechanism. Combined X\u2010ray crystallography, nuclear magnetic resonance (NMR), and computational data support the aromatic character of the ferrabenzene ring in compounds\n                    <jats:bold>5a\u2010c<\/jats:bold>\n                    and, to a lesser extent, in their precursors\n                    <jats:bold>4a\u2010c<\/jats:bold>\n                    . Complexes\n                    <jats:bold>4a\u2010c<\/jats:bold>\n                    and\n                    <jats:bold>5a\u2010c<\/jats:bold>\n                    were further characterized by IR spectroscopy, mass spectrometry, and IR spectroelectrochemistry. A selection of ferrabenzenes (\n                    <jats:bold>5a<\/jats:bold>\n                    ,\n                    <jats:bold>5b<\/jats:bold>\n                    ,\n                    <jats:bold>5aEt<\/jats:bold>\n                    ) revealed physicochemical properties suitable for biological applications, including permanent air stability, adequate aqueous solubility and stability, and balanced hydrophilic\/lipophilic profile. These compounds exhibited potent cytotoxicity in vitro against three cancer cell lines, with\n                    <jats:bold>5aEt<\/jats:bold>\n                    standing out for its pronounced activity, attributed to disruption of cell redox homeostasis, and marked selectivity compared to two noncancerous cell lines.\n                  <\/jats:p>","DOI":"10.1002\/anie.202510795","type":"journal-article","created":{"date-parts":[[2025,10,9]],"date-time":"2025-10-09T13:14:09Z","timestamp":1760015649000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Multicomponent Synthesis on a Diiron Platform of Stable Ferrabenzenes with Promising Anticancer Activity"],"prefix":"10.1002","volume":"64","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3465-8559","authenticated-orcid":false,"given":"Sara","family":"Benetti","sequence":"first","affiliation":[{"name":"Department of Chemistry and Industrial Chemistry University of Pisa  Via G. Moruzzi 13 Pisa 56124 Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9543-6127","authenticated-orcid":false,"given":"Tommaso","family":"Nottoli","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Industrial Chemistry University of Pisa  Via G. Moruzzi 13 Pisa 56124 Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhimei","family":"Xiao","sequence":"additional","affiliation":[{"name":"Chimie ParisTech CNRS, Institute of Chemistry for Life and Health Sciences, Laboratory for Inorganic Chemical Biology PSL University  Paris 75005 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tiziana","family":"Funaioli","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Industrial Chemistry University of Pisa  Via G. Moruzzi 13 Pisa 56124 Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0739-0518","authenticated-orcid":false,"given":"Stefano","family":"Zacchini","sequence":"additional","affiliation":[{"name":"Department of Industrial Chemistry \u201cToso Montanari\u201d University of Bologna  Via P. Gobetti 85 Bologna 40129 Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4244-5097","authenticated-orcid":false,"given":"Gilles","family":"Gasser","sequence":"additional","affiliation":[{"name":"Chimie ParisTech CNRS, Institute of Chemistry for Life and Health Sciences, Laboratory for Inorganic Chemical Biology PSL University  Paris 75005 France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4947-3912","authenticated-orcid":false,"given":"Filippo","family":"Lipparini","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Industrial Chemistry University of Pisa  Via G. Moruzzi 13 Pisa 56124 Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3683-8708","authenticated-orcid":false,"given":"Fabio","family":"Marchetti","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Industrial Chemistry University of Pisa  Via G. 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