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However, conventional POS synthesis via strong acid\u2013base neutralization (e.g., \u2500SO\u2083H and \u2500NH\u2082) leads to extensive hydrogen bonding with water, compromising stability in aqueous and water\u2010lean environments. Here, we address this challenge by designing POSs with hydrophobic porous channels and minimal hydrogen bonding formation. Our key innovation is the use of fluorinated tetrazole as a weak acid tecton and a tetra\u2010substituted imidazole precursor devoid of active protons as the base. Single\u2010crystal analysis and computational modeling reveal that the structural integrity of the synthesized POSs arises primarily from cation\u2013anion interactions, with water confined as clusters in the pores, independent of hydrogen bonding with the scaffold. Robustness of the POS structure under aqueous and water\u2010lean conditions is confirmed by X\u2010ray and neutron scattering, as well as computational modeling, confirming preserved packing and crystal structures. The stability of POS is further demonstrated in aqueous iodine capture, with imidazolium cations and C\u2013F functionalizations serving as strong adsorption sites. The approach developed herein further pushes the boundary of POS materials to withstand both aqueous and water\u2010lean conditions.<\/jats:p>","DOI":"10.1002\/anie.202510966","type":"journal-article","created":{"date-parts":[[2025,7,23]],"date-time":"2025-07-23T08:17:47Z","timestamp":1753258667000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Constructing Water\u2010Stable Porous Organic Salts via Suppressed Proton Integration Using Fluorinated Tetrazole Tectons"],"prefix":"10.1002","volume":"64","author":[{"given":"Errui","family":"Li","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Tennessee Knoxville  Knoxville TN 37996 USA"},{"name":"Chemical Sciences Division Oak Ridge National Laboratory  Oak Ridge TN 37831 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xian","family":"Suo","sequence":"additional","affiliation":[{"name":"ZJU\u2010Hangzhou Global 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