{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,11]],"date-time":"2026-03-11T20:11:03Z","timestamp":1773259863567,"version":"3.50.1"},"reference-count":40,"publisher":"Wiley","issue":"43","license":[{"start":{"date-parts":[[2025,9,1]],"date-time":"2025-09-01T00:00:00Z","timestamp":1756684800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52171218"],"award-info":[{"award-number":["52171218"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52271222"],"award-info":[{"award-number":["52271222"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22379096"],"award-info":[{"award-number":["22379096"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52371230"],"award-info":[{"award-number":["52371230"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,10,20]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Nitride family compounds are among the earliest explored materials for solid electrolytes (SEs). The main challenge lies in effectively enhancing their electrochemical stability without compromising their excellent Li\u2010ion conductivity and Li metal compatibility. Herein, a H<jats:italic><jats:sup>\u03b4<\/jats:sup><\/jats:italic><jats:sup>\u2212<\/jats:sup>\u2013H<jats:italic><jats:sup>\u03b4<\/jats:sup><\/jats:italic><jats:sup>+<\/jats:sup> comproportionation reaction between LiH and NH<jats:sub>4<\/jats:sub>F is employed to synthesize a Li\u2013N\u2013H\u2013F complex, consisting of Li<jats:sub>2+<\/jats:sub><jats:italic><jats:sub>x<\/jats:sub><\/jats:italic>NHF<jats:italic><jats:sub>x<\/jats:sub><\/jats:italic> matrix and dispersed LiF nanoparticles. Density functional calculation results show that the incorporated F atoms in Li<jats:sub>2<\/jats:sub>NH lattice lead to structural variation and electron density redistribution, providing a more connected Li\u2010ion network with low migration energy barriers. More importantly, the interfacial side reactions between the Li\u2013N\u2013H\u2013F complex and electrodes are strongly self\u2010limited due to the blocking effect of the in situ formed Li<jats:sub>4<\/jats:sub>NH\/LiF\u2010enriched interphases. The newly identified interphase Li<jats:sub>4<\/jats:sub>NH exhibits fast Li\u2010ion migration ability and intrinsic stability toward Li, facilitating stable Li plating\/stripping. Based on the superiority in Li\u2010ion conduction and electrode compatibility, the Li\u2013N\u2013H\u2013F solid electrolyte films prepared via cold pressing with 0.5 wt% binder enable stable cycling of Li||Li, Li||TiS<jats:sub>2<\/jats:sub>, and Li||LiCoO<jats:sub>2<\/jats:sub> all\u2010solid\u2010state batteries.<\/jats:p>","DOI":"10.1002\/anie.202511344","type":"journal-article","created":{"date-parts":[[2025,9,2]],"date-time":"2025-09-02T06:30:06Z","timestamp":1756794606000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["H<i><sup>\u03b4<\/sup><\/i><sup>\u2212<\/sup>\u2013H<i><sup>\u03b4<\/sup><\/i><sup>+<\/sup> Comproportionation Enables Stable Li\u2013N\u2013H\u2013F Solid Electrolyte"],"prefix":"10.1002","volume":"64","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0350-6579","authenticated-orcid":false,"given":"Yuepeng","family":"Pang","sequence":"first","affiliation":[{"name":"School of Materials and Chemistry University of Shanghai for Science and Technology  Shanghai 200093 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chao","family":"Wei","sequence":"additional","affiliation":[{"name":"School of Materials and Chemistry University of Shanghai for Science and Technology  Shanghai 200093 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiangyang","family":"Ye","sequence":"additional","affiliation":[{"name":"School of Materials and Chemistry University of Shanghai for Science and Technology  Shanghai 200093 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xin","family":"Li","sequence":"additional","affiliation":[{"name":"School of Materials and Chemistry University of Shanghai for Science and Technology  Shanghai 200093 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hao","family":"Sun","sequence":"additional","affiliation":[{"name":"School of Materials and Chemistry University of Shanghai for Science and Technology  Shanghai 200093 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sainan","family":"Luo","sequence":"additional","affiliation":[{"name":"School of Materials and Chemistry University of Shanghai for Science and Technology  Shanghai 200093 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Taiqiang","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Materials and Chemistry University of Shanghai for Science and Technology  Shanghai 200093 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shuixin","family":"Xia","sequence":"additional","affiliation":[{"name":"School of Materials and Chemistry University of Shanghai for Science and Technology  Shanghai 200093 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tao","family":"Yuan","sequence":"additional","affiliation":[{"name":"School of Materials and Chemistry University of Shanghai for Science and Technology  Shanghai 200093 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6614-9567","authenticated-orcid":false,"given":"Shiyou","family":"Zheng","sequence":"additional","affiliation":[{"name":"School of Materials and Chemistry University of Shanghai for Science and Technology  Shanghai 200093 China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2025,9]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-021-04139-1"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202307243"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2016.103"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202108397"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.esci.2022.02.008"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2019.03.019"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abj7698"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat3066"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202304530"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9EE02311A"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-023-05899-8"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201809219"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202304285"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.9b01326"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202406632"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.89283"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-024-01813-z"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c02170"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2024.110439"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202415847"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/0375-9601(79)90846-6"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2CP23636B"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.4952601"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.8b10528"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1007\/s41918-020-00092-1"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202407923"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-020-00845-5"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2019.09.022"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202413591"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202202731"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2022.12.003"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.esci.2022.02.002"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.8b07704"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aau9245"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtnano.2020.100079"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevMaterials.8.015403"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature01210"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19976231215"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.81.104113"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202407882"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202511344","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,18]],"date-time":"2025-10-18T17:12:50Z","timestamp":1760807570000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202511344"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,9]]},"references-count":40,"journal-issue":{"issue":"43","published-print":{"date-parts":[[2025,10,20]]}},"alternative-id":["10.1002\/anie.202511344"],"URL":"https:\/\/doi.org\/10.1002\/anie.202511344","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,9]]},"assertion":[{"value":"2025-05-27","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-08-20","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-09-01","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202511344"}}