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This transformation provides direct access to synthetically valuable 1,3\u2010dibromo compounds with excellent atom economy under mild reaction conditions. The protocol demonstrates remarkable versatility, exhibiting broad substrate scope and excellent functional group compatibility. Notably, the obtained 1,3\u2010dibromo products function as highly versatile synthetic building blocks. Through rationally designed one\u2010pot multistep transformations, these intermediates can be conveniently converted into structurally diverse derivatives, including oxetanes and allyl bromides, directly from terminal alkenes.\n                  <\/jats:p>","DOI":"10.1002\/anie.202511486","type":"journal-article","created":{"date-parts":[[2025,8,19]],"date-time":"2025-08-19T12:40:45Z","timestamp":1755607245000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Visible\u2010Light\u2010Driven Iron\u2010Catalyzed Atom Transfer Radical Addition of CH\n                    <sub>2<\/sub>\n                    Br\n                    <sub>2<\/sub>\n                    to Alkenes: Facile Access to 1,3\u2010Dibromo Compounds"],"prefix":"10.1002","volume":"64","author":[{"given":"Ning","family":"Yan","sequence":"first","affiliation":[{"name":"State Key Laboratory of Fine Chemicals Dalian University of Technology  Dalian 116023 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