{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,20]],"date-time":"2026-10-20T22:08:54Z","timestamp":1792534134393,"version":"4.5.0"},"reference-count":50,"publisher":"Wiley","issue":"38","license":[{"start":{"date-parts":[[2025,7,31]],"date-time":"2025-07-31T00:00:00Z","timestamp":1753920000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,7,31]],"date-time":"2025-07-31T00:00:00Z","timestamp":1753920000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2023YFB4004900"],"award-info":[{"award-number":["2023YFB4004900"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["62305005 62321004"],"award-info":[{"award-number":["62305005 62321004"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["62227817"],"award-info":[{"award-number":["62227817"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004826","name":"Natural Science Foundation of Beijing Municipality","doi-asserted-by":"publisher","award":["Z200004"],"award-info":[{"award-number":["Z200004"]}],"id":[{"id":"10.13039\/501100004826","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,9,15]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The reverse water\u2013gas shift (RWGS) reaction presents an industrial promise for carbon dioxide valorization. In this work, a dual\u2010site Ru\u2010RuO\n                    <jats:sub>2<\/jats:sub>\n                    cocatalyst anchored on Si\u2010supported GaN nanowires (NWs) is developed for solar\u2010powered CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010to\u2010CO conversion. The assembled Si\u2010supported GaN NWs\/Ru\u2010RuO\n                    <jats:sub>2<\/jats:sub>\n                    delivers a considerable CO rate of 57.89\u00a0mmol\u00b7cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    \u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    with nearly 100% selectivity under illumination at 5.5\u00a0W\u00b7cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    without external heating, along with a remarkable turnover frequency of 2.28\u00a0\u00d7\u00a010\n                    <jats:sup>5<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    . The temperature\u2010programmed desorption, in situ spectroscopic characterization, and DFT calculations collectively reveal that the Si\u2010supported GaN NWs\/Ru\u2010RuO\n                    <jats:sub>2<\/jats:sub>\n                    enables simultaneous activation of CO\n                    <jats:sub>2<\/jats:sub>\n                    and H\n                    <jats:sub>2<\/jats:sub>\n                    . Moreover, the synergy between Ru\u2010RuO\n                    <jats:sub>2<\/jats:sub>\n                    and GaN substantially reduces the reaction energy barrier from 0.83 to 0.64\u00a0eV via the key *COOH intermediate, thereby establishing a new benchmark for light\u2010driven RWGS efficiency. This work provides a strategic design for high\u2010performance CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010to\u2010CO conversion and opens avenues for downstream synthetic applications.\n                  <\/jats:p>","DOI":"10.1002\/anie.202511886","type":"journal-article","created":{"date-parts":[[2025,7,31]],"date-time":"2025-07-31T11:45:37Z","timestamp":1753962337000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Ru\u2010RuO\n                    <sub>2<\/sub>\n                    Coordinated with Si\u2010Supported GaN Nanowires for Light\u2010Driven Simultaneous Activation of CO\n                    <sub>2<\/sub>\n                    and H\n                    <sub>2<\/sub>\n                    to Achieve Exceptional Reverse Water\u2013Gas Shift Reaction"],"prefix":"10.1002","volume":"64","author":[{"given":"Jiaming","family":"Liu","sequence":"first","affiliation":[{"name":"Key Laboratory for Power Machinery and Engineering of Ministry of Education Research Center for Renewable Synthetic Fuel School of Mechanical Engineering Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 China"},{"name":"Institute of Eco\u2010Chongming  20 Cuiniao Road, Chongming Shanghai 202162 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zijian","family":"Huang","sequence":"additional","affiliation":[{"name":"China\u2010UK Low Carbon College Shanghai Jiao Tong University  No.3 Yinlian Road, Lingang Shanghai 201306 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiantong","family":"Zheng","sequence":"additional","affiliation":[{"name":"College of Instrument Science and Opto\u2010electronics Engineering Beijing Information Science and Technology University  Beijing 100096 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Muhammad Salman","family":"Nasir","sequence":"additional","affiliation":[{"name":"Key Laboratory for Power Machinery and Engineering of Ministry of Education Research Center for Renewable Synthetic Fuel School of Mechanical Engineering Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ding","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory for Power Machinery and Engineering of Ministry of Education Research Center for Renewable Synthetic Fuel School of Mechanical Engineering Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ping","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Artificial Microstructure and Mesoscopic Physics School of Physics Nano\u2010Optoelectronics Frontier Center of Ministry of Education (NFC\u2010MOE) Peking University  Beijing 10087 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinglin","family":"Li","sequence":"additional","affiliation":[{"name":"Key Laboratory for Power Machinery and Engineering of Ministry of Education Research Center for Renewable Synthetic Fuel School of Mechanical Engineering Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yixin","family":"Li","sequence":"additional","affiliation":[{"name":"Key Laboratory for Power Machinery and Engineering of Ministry of Education Research Center for Renewable Synthetic Fuel School of Mechanical Engineering Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Zhu","sequence":"additional","affiliation":[{"name":"Key Laboratory for Power Machinery and Engineering of Ministry of Education Research Center for Renewable Synthetic Fuel School of Mechanical Engineering Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinqiang","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Artificial Microstructure and Mesoscopic Physics School of Physics Nano\u2010Optoelectronics Frontier Center of Ministry of Education (NFC\u2010MOE) Peking University  Beijing 10087 China"},{"name":"Peking University Yangtze Delta Institute of Optoelectronics  Nantong Jiangsu 226010 China"},{"name":"Collaborative Innovation Center of Quantum Matter School of Physics Peking University  Beijing 100871 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhen","family":"Huang","sequence":"additional","affiliation":[{"name":"Key Laboratory for Power Machinery and Engineering of Ministry of Education Research Center for Renewable Synthetic Fuel School of Mechanical Engineering Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2476-0322","authenticated-orcid":false,"given":"Baowen","family":"Zhou","sequence":"additional","affiliation":[{"name":"Key Laboratory for Power Machinery and Engineering of Ministry of Education Research Center for Renewable Synthetic Fuel School of Mechanical Engineering Shanghai Jiao Tong University  800 Dongchuan Road Shanghai 200240 China"},{"name":"Institute of Eco\u2010Chongming  20 Cuiniao Road, Chongming Shanghai 202162 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,7,31]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s43586-023-00243-w"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abn7950"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.2c02179"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11708-024-0936-6"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11708-024-0964-2"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5EE02657A"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4SC01530D"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TA03480D"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-42757-7"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202203836"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-023-01040-0"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202308005"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c02041"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5TA00809C"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202101667"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.6b00119"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c02139"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-023-01023-1"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scib.2024.11.021"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11708-023-0881-9"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA07364B"},{"key":"e_1_2_7_22_1","first-page":"739","volume":"66","author":"Zhou B.","year":"2023","journal-title":"Sci. China Chem."},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202405904"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2025.125051"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202309906"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202413528"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-45389-7"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201702277"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202411813"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11708-024-0950-8"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202503608"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202503733"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c01876"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-57954-9"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.155203"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.4c06427"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.3390\/catal9020108"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.150486"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.2c01506"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202420796"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.120838"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scib.2022.10.001"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/sia.5852"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-024-07665-w"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201900658"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c03360"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00726"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202505244"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c04262"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202405835"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202511886","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202511886","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202511886","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,10]],"date-time":"2026-10-10T15:50:33Z","timestamp":1791647433000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202511886"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,7,31]]},"references-count":50,"journal-issue":{"issue":"38","published-print":{"date-parts":[[2025,9,15]]}},"alternative-id":["10.1002\/anie.202511886"],"URL":"https:\/\/doi.org\/10.1002\/anie.202511886","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,7,31]]},"assertion":[{"value":"2025-05-30","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-07-18","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-07-31","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202511886"}}