{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,28]],"date-time":"2026-08-28T00:03:17Z","timestamp":1787875397075,"version":"build-2784847793"},"reference-count":64,"publisher":"Wiley","issue":"49","license":[{"start":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T00:00:00Z","timestamp":1760054400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T00:00:00Z","timestamp":1760054400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2025,12,1]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Ni\u2013N\n                    <jats:sub>4<\/jats:sub>\n                    \u2013PAN\u2013NC, consisting of an atomic Ni\u2013N\n                    <jats:sub>4<\/jats:sub>\n                    \u00a0site, mimics the intramolecular electron\u2010harnessing of natural laccase (LAC) confined in a zeolitic imidazolate framework\u20108 (LAC@ZIF\u20108) for anodic electrooxidation of bisphenol\u2010A (BPA). We have introduced a facile \u03c0\u2010conjugated unit of polyacrylonitrile (PAN)\u2010resorcinol\u2010derived N\u2010doped conjugated \u2010C\u2261N. The atomically dispersed Ni\u2010single\u2010atom in Ni\u2013N\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sup>\u2010<\/jats:sup>\n                    PAN\u2013NC exhibits high activity for the paired electrolysis of ORR and the electrooxidation of BPA with an enhanced current density. The single Ni\u2013N\n                    <jats:sub>4\u2013<\/jats:sub>\n                    PAN\u2013NC electrode effectively withdraws the electrons from electrooxidizing BPA due to a built\u2010in electric field via incorporation of Ni\u2013N\n                    <jats:sub>4<\/jats:sub>\n                    . The paired electrolysis of Ni\u2013N\n                    <jats:sub>4\u2013<\/jats:sub>\n                    PAN\u2013NC biofuel cells is determined by LSV, EIS, and power\u2010polarization curve\u00a0for anodic electrooxidation of BPA. Machine learning molecular dynamics (ML\u2010MD) simulation depicts non\u2010covalent interaction (hydrogen bonding) between the O\u2010hydroxyl of BPA and the N of the Ni\u2013N\n                    <jats:sub>4\u2013<\/jats:sub>\n                    PAN\u2013NC, suggesting\u00a0preferential adsorption\u00a0on\u00a0the Ni\u2013N\n                    <jats:sub>4\u2013<\/jats:sub>\n                    PAN\u2013NC surface via weak van der Waals interactions and \u03c0\u2013\u03c0 stacking between the aromatic rings of BPA and the conjugated PAN\u2010NC. An increased power density with increased concentration of BPA in the absence of ABTS suggests a DET mechanism of BPA electrooxidation on Ni\u2013N\n                    <jats:sub>4<\/jats:sub>\n                    , unlike a MET in the presence of ABTS when using LAC@ZIF\u20108. Thus, single atomic\u00a0Ni\u00a0\u2212\u00a0N\n                    <jats:sub>4<\/jats:sub>\n                    \u00a0opens avenues with\u00a0a DET mechanism.\n                  <\/jats:p>","DOI":"10.1002\/anie.202511892","type":"journal-article","created":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T08:23:13Z","timestamp":1760084593000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Single\u2010Atomic Ni\u2010N\n                    <sub>4<\/sub>\n                    Biofuel Cell for Mimicking Intramolecular Electron\u2010Harnessing of Laccase"],"prefix":"10.1002","volume":"64","author":[{"given":"Tapan","family":"Dey","sequence":"first","affiliation":[{"name":"Electrochemical Energy &amp; Sensor Research Laboratory Amity Institute of Click Chemistry Research &amp; Studies Amity University  Noida India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anubha","family":"Yadav","sequence":"additional","affiliation":[{"name":"Electrochemical Energy &amp; Sensor Research Laboratory Amity Institute of Click Chemistry Research &amp; Studies Amity University  Noida India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Novotna","family":"Seal","sequence":"additional","affiliation":[{"name":"Research Institute for Sustainable Energy Centres for Research and Education in Science and Technology (TCG\u2010CREST), Salt Lake  Kolkata India"},{"name":"Academy of Scientific and Innovative Research (AcSIR)  Ghaziabad 201002 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9640-1567","authenticated-orcid":false,"given":"Babasaheb M.","family":"Matsagar","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering National Taiwan University  No. 1, Sec. 4, Roosevelt Road Taipei 106319 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-7743-4802","authenticated-orcid":false,"given":"Norman C.\u2010R.","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering National Taiwan University  No. 1, Sec. 4, Roosevelt Road Taipei 106319 Taiwan"},{"name":"Molecular Science and Technology Program Taiwan International Graduate Program Academia Sinica  Taiwan"},{"name":"International Graduate Program of Molecular Science and Technology (NTU\u2010MST) National Taiwan University  Taipei 10617 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Praveen","family":"Yadav","sequence":"additional","affiliation":[{"name":"Synchrotron X\u2010ray Facility Raja Ramanna Centre for Advanced Technology  Rajendra Nagar Indore Madhya Pradesh 452013 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0590-1396","authenticated-orcid":false,"given":"Kevin C.\u2010W.","family":"Wu","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering National Taiwan University  No. 1, Sec. 4, Roosevelt Road Taipei 106319 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Amreen","family":"Bano","sequence":"additional","affiliation":[{"name":"Research Institute for Sustainable Energy Centres for Research and Education in Science and Technology (TCG\u2010CREST), Salt Lake  Kolkata India"},{"name":"Academy of Scientific and Innovative Research (AcSIR)  Ghaziabad 201002 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0868-194X","authenticated-orcid":false,"given":"Saikat","family":"Dutta","sequence":"additional","affiliation":[{"name":"Electrochemical Energy &amp; Sensor Research Laboratory Amity Institute of Click Chemistry Research &amp; Studies Amity University  Noida India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,10,10]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202420994"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202407261"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtener.2024.101706"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202316824"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-45527-1"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nantod.2024.102315"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-31406-0"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202400676"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4TA05493H"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2021.02.004"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-27640-7"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.149772"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.148429"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202200957"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-46175-1"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE03383J"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.3c01310"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202213863"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202205639"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c02968"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.3c03638"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.4c04469"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.3c11378"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.141657"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.checat.2023.100528"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-17018-6"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c00516"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-14210-1"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.analchem.3c05161"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202400629"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202415933"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202202485"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201903125"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202424552"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202111322"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c03814"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-59079-5"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matchemphys.2025.130837"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2019.104308"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b13149"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-50123-4"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202401029"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202404633"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202410326"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.3c00444"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cossms.2025.101214"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp992433y"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.98.146401"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.108.058301"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ces.2021.117383"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.0c00472"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201902765"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.2c06778"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1088\/1361-648X\/aa680e"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.47.558"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1016\/0927-0256(96)00008-0"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.50.17953"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.77.3865"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.44.943"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1088\/0953-8984\/9\/4\/002"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.3c01182"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1038\/srep21396"},{"key":"e_1_2_7_63_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-62062-9"},{"key":"e_1_2_7_64_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.145973"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202511892","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.202511892","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.202511892","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,5,23]],"date-time":"2026-05-23T12:29:11Z","timestamp":1779539351000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.202511892"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,10,10]]},"references-count":64,"journal-issue":{"issue":"49","published-print":{"date-parts":[[2025,12,1]]}},"alternative-id":["10.1002\/anie.202511892"],"URL":"https:\/\/doi.org\/10.1002\/anie.202511892","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,10,10]]},"assertion":[{"value":"2025-05-30","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-09-22","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-10-10","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202511892"}}