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Herein, we designed a SiO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010induced loose CeO\n                    <jats:sub>2<\/jats:sub>\n                    as an effective capture for Pt atoms. The abundant surface O vacancies in the loose CeO\n                    <jats:sub>2<\/jats:sub>\n                    can trigger significant electron transfer from Pt to CeO\n                    <jats:sub>2<\/jats:sub>\n                    and play a crucial role in stabilizing Pt atoms, therefore, largely improving its thermal stability. The as\u2010synthesized Pt\u2010aCeO\n                    <jats:sub>2<\/jats:sub>\n                    @SiO\n                    <jats:sub>2<\/jats:sub>\n                    catalyst possesses a record CO production rate of 7672.7\u00a0mol\n                    <jats:sub>CO<\/jats:sub>\n                    mol\n                    <jats:sub>Pt<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    with CO selectivity\u00a0&gt;\u00a097% at 400\u00a0\u00b0C surpass most of the reported Pt\u2010based catalysts. More importantly, over 90% of the initial activity of the catalyst remains after 200\u00a0h constant operation at 400\u00a0\u00b0C, verifying the improved durability of Pt atoms under high temperature. Our investigation proposes a method of inducing the formation of defect\u2010rich active supports through amorphous substrates, providing new thinking for designing atomic catalysts with good stability under high temperatures.\n                  <\/jats:p>","DOI":"10.1002\/anie.202511913","type":"journal-article","created":{"date-parts":[[2025,9,6]],"date-time":"2025-09-06T07:45:57Z","timestamp":1757144757000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["Amorphous Silica Induced Loose CeO\n                    <sub>2<\/sub>\n                    Clusters with Isolated Pt Atoms for Efficient Reverse\u2010Water Gas Shift Reaction"],"prefix":"10.1002","volume":"64","author":[{"given":"Jiwei","family":"Lei","sequence":"first","affiliation":[{"name":"College of Polymer Science and Engineering State Key Laboratory of Advanced Polymer Materials Sichuan University Chengdu 610065 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