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In this work, we tailored the solid\u2013liquid phase transport interface by adding covalent organic frameworks quantum dots (COFs QDs) into electrolyte. COFs QDs with abundant lipophilic ether\u2010oxygen groups and \u223c12\u00a0nm nano\u2010size can serve as myriad ion\u2010transport nano\u2010engines for constantly replenishing the interface with Li\n                    <jats:sup>+<\/jats:sup>\n                    to achieve near\u2010frictionless ion transport (\n                    <jats:italic>t<\/jats:italic>\n                    <jats:sub>Li<\/jats:sub>\n                    <jats:sup>+<\/jats:sup>\n                    \u00a0=\u00a00.98) and exceptional stability (&gt;400 days). Lithium\u2013sulfur battery based on COFs QDs shows high discharge specific capacity of 1063.7\u00a0mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    after 100 cycles at 0.2\u00a0C and maintains a low overpotential (\u223c16\u00a0mV) over 4000\u00a0h at 1\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    with 1\u00a0mAh cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    in Li\/\/Li symmetric battery. A Li\u2013S pouch battery has also been successfully assembled to validate the practicality. Our results may promote the development of COFs QDs in energy storage field.\n                  <\/jats:p>","DOI":"10.1002\/anie.202512031","type":"journal-article","created":{"date-parts":[[2025,8,19]],"date-time":"2025-08-19T13:43:56Z","timestamp":1755611036000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Covalent Organic Framework Quantum Dots for Near\u2010Frictionless Ion Transport Battery Electrolyte"],"prefix":"10.1002","volume":"64","author":[{"given":"Can","family":"Guo","sequence":"first","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Carbon Dioxide Resource Utilization School of Chemistry South China Normal University  Guangzhou 510006 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pan","family":"Xue","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Yangzhou University  Yangzhou 225127 P.R. 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