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However, sluggish kinetics, low selectivity and efficiency hinder practical application. Herein, we demonstrate an integrated ECR||MOR system employing CuBi cathode and NiCo anode for energy\u2010efficient FA cogeneration. The CuBi alloy achieves high Faradaic efficiencies (FE\u00a0&gt;\u00a090%) for FA generation over an extensive potential range (&gt;400\u00a0mV), attributed to the accelerated formation of HCOO\n                    <jats:sup>*<\/jats:sup>\n                    intermediates in facilitating FA production. Meanwhile, the NiCo alloy reached a remarkable FE of 97.5% for FA generation at 1.4\u00a0V versus reversible hydrogen electrode, benefiting from rapid HCOO\n                    <jats:sup>*<\/jats:sup>\n                    intermediate formation that effectively mitigates CO toxicity. This unique system delivered a current density of 10\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at a voltage of 2.07\u00a0V, representing a substantial reduction of 320\u00a0mV compared to water electrolysis. Across a wide operational voltage window (2.0\u20132.8\u00a0V), the system consistently delivered total Faradaic efficiencies ranging between 189% and 192%, alongside exceptional FA production capacities surpassing 400\u00a0g kWh\n                    <jats:sup>\u22121<\/jats:sup>\n                    , which significantly outperformed traditional methods (\u223c220\u00a0g kWh\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). This work provides an efficient pathway for low\u2010energy CO\n                    <jats:sub>2<\/jats:sub>\n                    utilization and sustainable FA production.\n                  <\/jats:p>","DOI":"10.1002\/anie.202512078","type":"journal-article","created":{"date-parts":[[2025,9,6]],"date-time":"2025-09-06T07:48:47Z","timestamp":1757144927000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":37,"title":["Harnessing Electrocatalytic Coupling of Carbon Dioxide and Methanol for High\u2010Efficiency Formic Acid Production"],"prefix":"10.1002","volume":"64","author":[{"given":"Zhikeng","family":"Zheng","sequence":"first","affiliation":[{"name":"School of Environmental Science and Engineering Sun Yat\u2010sen University  Guangzhou 510275 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaobo","family":"Zheng","sequence":"additional","affiliation":[{"name":"Center for Clean Energy Technology School of Mathematical and Physical Sciences Faculty of Science University of Technology Sydney  Sydney New South Wales 2007 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ligang","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute of Molecular Plus Tianjin University  Tianjin 300072 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huiming","family":"Wen","sequence":"additional","affiliation":[{"name":"School of Environmental Science and Engineering Sun Yat\u2010sen University  Guangzhou 510275 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ke","family":"Li","sequence":"additional","affiliation":[{"name":"School of Environmental Science and Engineering Sun Yat\u2010sen University  Guangzhou 510275 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenhao","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Environmental Science and Engineering Sun Yat\u2010sen University  Guangzhou 510275 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yameng","family":"Fan","sequence":"additional","affiliation":[{"name":"Centre for Atomaterials and Nanomanufacturing (CAN) School of Science RMIT University  Melbourne VIC 3000 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peng","family":"Li","sequence":"additional","affiliation":[{"name":"Centre for Atomaterials and Nanomanufacturing (CAN) School of Science RMIT University  Melbourne VIC 3000 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Suyu","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Environmental Science and Engineering Sun Yat\u2010sen University  Guangzhou 510275 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bin","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Environmental Science and Engineering Sun Yat\u2010sen University  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