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However, designing an electrocatalyst with high activity and selectivity, resistance to seawater corrosion, and even stable operation at industrial currents (\u2265300\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ), remains a critical challenge. In this work, we report a pentagonal defect\u2010rich nanocarbon with chlorine\u2010doping (Cl\u2010PDC) by tailoring fullerene (C\n                    <jats:sub>60<\/jats:sub>\n                    ) precursors via the molten salt method. The as\u2010prepared Cl\u2010PDC catalyst achieves a record H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    yield of 74.61\u00a0mol g\n                    <jats:sub>cat<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    at a current density of 800\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    with a nearly 100% Faradaic efficiency, outperforming among all previously reported catalysts in simulated seawater or neutral environments. Remarkably, the Cl\u2010PDC\u2010based electrode maintains operational stability over 400 h in simulated seawater, and enables rapid disinfection and pollutant degradation. Theoretical calculations and experimental analysis reveal that the synergy between the intrinsic pentagonal defects and Cl doping modulates the electronic structure of the carbon framework, optimizing *OOH intermediate adsorption, and introduces the localized negative charge to suppress Cl\n                    <jats:sup>\u2212<\/jats:sup>\n                    poisoning at active sites. This work paves the way for sustainable seawater H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    production and marine environmental protection.\n                  <\/jats:p>","DOI":"10.1002\/anie.202512138","type":"journal-article","created":{"date-parts":[[2025,11,28]],"date-time":"2025-11-28T05:45:46Z","timestamp":1764308746000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":23,"title":["Seawater Electrosynthesis of Hydrogen Peroxide at Industrial\u2010level Current Densities Enabled by Pentagonal Defect\u2010Rich Nanocarbon with Chlorine Doping"],"prefix":"10.1002","volume":"65","author":[{"given":"Hongshang","family":"Hu","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering Hainan University  Haikou 570228 China"},{"name":"School of Chemistry and Chemical Engineering Huazhong University of Science and Technology  Wuhan 430074 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chang","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Hainan University  Haikou 570228 China"},{"name":"School of Materials Science and Engineering Huazhong University of Science and Technology  Wuhan 430074 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huiyao","family":"Qi","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Huazhong University of Science and Technology  Wuhan 430074 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lilong","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Huazhong University of Science and Technology  Wuhan 430074 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Muneerah","family":"Alomar","sequence":"additional","affiliation":[{"name":"Department of Physics College of Science Princess Nourah bint Abdulrahman University  P. 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Box 84428 Riyadh 11671 Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lipiao","family":"Bao","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Huazhong University of Science and Technology  Wuhan 430074 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xing","family":"Lu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Hainan University  Haikou 570228 China"},{"name":"School of Materials Science and Engineering Huazhong University of Science and Technology  Wuhan 430074 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7584-3799","authenticated-orcid":false,"given":"Jian","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Hainan University  Haikou 570228 China"},{"name":"School of Chemistry and Chemical Engineering Huazhong University of 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