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As unraveled by in situ spectral investigations and theoretical calculations, the core@satellites microstructure enables the tandem ECO\n                    <jats:sub>2<\/jats:sub>\n                    RR pathway to happen at the interfaced Ag and AgCu sites to facilitate C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    OH formation, with Faradaic efficiency (FE) for C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    OH reaching 61.4% at \u2212100\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . Under light, an intensive localized electric field could be excited in the near\u2010surface region of Ag@AgCu core@satellites, contributing to the increased surface *CO coverage, lowered *COCOH formation barrier and deceased *CHCOH\u2010to\u2010C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    OH conversion free energy. Thus, a high C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    OH selectivity (FE\u00a0=\u00a065.5%) at industrial\u2010level current density (\u2212280\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ) was achieved over Ag@AgCu core@satellites in a photo\u2010electrochemical flow cell.\n                  <\/jats:p>","DOI":"10.1002\/anie.202512179","type":"journal-article","created":{"date-parts":[[2025,8,18]],"date-time":"2025-08-18T12:36:31Z","timestamp":1755520591000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Plasmon\u2010Assisted Tandem Electrocatalysis for CO\n                    <sub>2<\/sub>\n                    \u2010to\u2010C\n                    <sub>2<\/sub>\n                    H\n                    <sub>5<\/sub>\n                    OH Conversion"],"prefix":"10.1002","volume":"64","author":[{"given":"Daixing","family":"Wei","sequence":"first","affiliation":[{"name":"International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University  Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yiqing","family":"Wang","sequence":"additional","affiliation":[{"name":"International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University  Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chung\u2010Li","family":"Dong","sequence":"additional","affiliation":[{"name":"Department of Physics Tamkang University  New Taipei City 25137 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ta Thi Thuy","family":"Nga","sequence":"additional","affiliation":[{"name":"Department of Physics Tamkang University  New Taipei City 25137 Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haotian","family":"Zhou","sequence":"additional","affiliation":[{"name":"International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University  Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenxi","family":"Hu","sequence":"additional","affiliation":[{"name":"International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University  Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuchuan","family":"Shi","sequence":"additional","affiliation":[{"name":"International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University  Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jialin","family":"Wang","sequence":"additional","affiliation":[{"name":"International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University  Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liejin","family":"Guo","sequence":"additional","affiliation":[{"name":"International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University  Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8536-7386","authenticated-orcid":false,"given":"Shaohua","family":"Shen","sequence":"additional","affiliation":[{"name":"International Research Center for Renewable Energy, State Key Laboratory of Multiphase Flow in Power Engineering Xi'an Jiaotong University  Xi'an 710049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,8,18]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aas9100"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.esci.2023.100136"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202306876"},{"key":"e_1_2_7_4_1","volume":"30","author":"Wan Z.\u2010X.","year":"2024","journal-title":"J. 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